I think brain tanned leather was used to some extent up until the 19th century or so -- I don't know to what extent. Brain tanned leather isn't fully tanned; it's just raw hide that has soaked up enough oil so it doesn't get hard. If it gets wet and stays wet for long it might well start to rot and stink. I think modern vegetable tanned leather has been in use for a long time, but not necessarily exclusively....
Modern commercial leather is either vegetable tanned or chrome tanned (though other processes are still used by amateurs). Vegetable tanned leather is very familiar to us knife knuts because nearly all leather knife sheaths are made of vegetable tanned leather. (I have seen a few very cheap sheaths made of thin chrome tanned leather.) Information on modern commercial leather is readily available. Information on what was used in past centuries is not so easy to find.




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