154 vs ATS34 is pretty much impossible, since they're almost completley identical. The maker/heattreat has more to do with any difference than actual steel.
S30V compared to the 2 above is difficult at first glance, but over time, the difference will show. First, the edge holding, then the way it sharpens.
VG10 feels very different to me, both in the edge (very bitey) and sharpening.
Never used BG42.
Mostly, advantages/disadvantages, and other characteristics only show after time and use, and sharpening. If I was given a few identical blades in different steels, I'm fairly confident that I could ID them, but only after significant use. But even then, I wouldn't be supprized if I guessed wrongly. As said previously, and by other people, differences have as much to do with the different makers as the steel itself. I know what Benchmade's 154CM is like, and I know what Spyderco's VG10 is like, but if BM made a knife in VG10 and Spyderco made one in 154CM (or an old ATS34 Military perhaps), damned if I'd know the difference if I wasn't told, or given ample opprotunity to test. I'd at the very least have to reprofile them myself, since the actual edge of the knife from the factory by each company is very different.