The reason water boils at a lower temp at the reduced pressure of higher elevation is that the molecules of water vapor can leave the surface faster, so the water doesn't have to "push" quite as hard to get the vapor moving. As a consequence, the vapor's ability to get pushed away easier means the water will "hold" less energy and results in a lower boiling temp.
Conversely, increase the pressure above the water by keeping it in a pressure cooker and it is harder to "push away" the vapor, so more energy stays in the water, allowing it to get hotter.
The technical description has to do with a concept called "vapor pressure". It is different for every substance and changes with temperature and pressure. Even solids have a vapor pressure as a few atoms/molecules of the material will always be in a gas above it.
Hope that isn't gibberish. Putting this stuff in everyday terms isn't my forte.

This is that part of chemistry/phyics called "Thermodynamics". If you seek further info, Google "Boyles Law".
Did you know that the reason you don't slide off a chair when you sit on it is because atoms of the seat of your pants actually overlap a bit into the atoms of the chair and vice versa? You are "atomically velcroed" into your seat. That's what makes "friction."

So, when someone tells you to "get your ass out of that chair", they mean it!
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