well, this is a traditional method to carburize the surface a few thousandths deep, but as a side effect you can get the rainbow coloration that is so prized on antique and replica guns. Pack polished and clean steel in a iron box with charcoal(supplies carbon), charred leather(supplies phosphorous), and some limestone gravel. bolt top on tightly, heat to red, and hold there for several hours. Quench from red heat to harden carburized surface. that's it in a nutshell. In practice I think it is a lot harder to get the effect. gunsmiths do this mostly. The surface coloration is not durable, but must be protected with lacquer for longest life. Also, in the 19th century when a lot of iron and non-hardenable mild steel was used for firearms(rendering questions of tempering moot)steel parts were "heat blued" by simply baking at a low temperature until the surface oxidizes blue, just as if you were tempering to a blue color. This is supposed to be a bright peacock blue obtainable no other way. I've seen photos of old gins, etc. treated like this, and it is a beautiful color. But again it is not too durable, just a surface effect. "Hot salt" bluing or "rust" bluing is much more durable and actually gives some protection to the surface from corrosion.