Ray Mears stuff while nice tends to aim at the general audience and as such its more of a Discovery Channel/Lonely Planet really.
There are a *few good episodes that concentrate a lot on skills but you would have to buy all the DVD's to see just a few things.
Ron Hoods are probably the best for actual hands on but Ron tends to deal with the rule of 'Nuff' good enough strong enough etc and because of that most of the items are rarely things of beauty, where, if you see Ray Mears make things they are usually very well made and crafted.
I only have experience with these two people, others here will undoubtedly chip in.
*Episodes: Aboriginal Britain from series 1
Birchbark Canoe, Sweden and Four seasons from Series 2