You really need the powder to do a loose piece canister.
You can fill a canister tightly with sheets of clean meatal and seal it, then weld it solid, but that isn't going to work for loose objects and ones with spaces. You will also need a big power hammer or press unless you look like Popeye.
The only way to make motorcycle chain damascus other than a canister weld is to take a sheet of steel ( 1084 is good) and tack weld the chain on it in rows. Then forge weld it down onto the core. This usually gets lots of bad welds and cold shuts, but it can be done by a competent smith.
The way to tell if the center is ready is to bring the whole billet up to welding temp and then soak for 10-15 minutes.