True 'Delrin', by Dupont, was originally invented as named in the 1950s. Case first started using it in 1967, with the first Sod Buster (2138 pattern). The 'synthetic' or 'composition' covers used by Case prior to that were of something different, and I've no idea what they used, prior to Delrin. A while back, I'd done some web searching on 'Delrin', and found that over the years/decades, Dupont has developed maybe dozens of different formulations of 'Delrin', each tailored to be useful in different applications (on their site even today, they list at least 85 formulations currently available). Some are made for greater toughness, others perhaps for strength, others for dimensional stability (resistance to shrinking), lubricity (for washers/bushings/etc), resistance to chemicals, heat, etc. So, it'd be hard to pin down exactly what type(s) Case might've used over the years, or if they even used similar materials from different mfrs, etc.
Pin cracks can happen if the cover materials are too thin, or if they're drilled too close to an edge, or whatever. So it's possible that manufacturing methods/practices might create issues from one maker that might not be seen in the same material from other makers. I could even see, if the Delrin covers are otherwise firmly attached to the scales themselves, near the ends, the anchor pinhole itself could be drilled to allow some movement of the spring's anchor pin, without stressing the Delrin cover and cracking it. So, as I see it, there are many ways to create an issue with cracking, and many ways to avoid it. May not depend as much on the material itself.