Matthew Gregory
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I've been seeing some posts that have a peculiar odor to them, so I thought I might take a brief moment and share this excerpt from one of the informative and highly readable pages on the Crucible Steel website. Hopefully it'll help shed some light for folks that are looking to know, rather than guess. I highlighted a couple of parts in bold to draw attention to some of the key parts. No big words, I promise!
Hardness of Carbides
Alloy elements (Cr, V, W, Mo) form hard carbide particles in tool steel microstructures.
The amount and type present influence the wear resistance.
HARDENED STEEL 60/65 HRC
CHROMIUM CARBIDES 66/68 HRC
MOLYBDENUM CARBIDES 72/77 HRC
TUNGSTEN CARBIDES 72/77 HRC
VANADIUM CARBIDES 82/84 HRC
Tool steels contain the element carbon, in levels from about 0.5% up to over 2%. The minimum level of about 0.5% is required to allow the steels to harden to the 60 HRC level during heat treating. The excess carbon above 0.5% plays little role in the hardening of the steels. Instead, it is intended to combine with other elements in the steel to form hard particles called carbides. Tool steels contain elements such as chromium, molybdenum, tungsten, and vanadium. These elements combine with the excess carbon to form chromium carbides, tungsten carbides, vanadium carbides, etc. These carbide particles are microscopic in size, and constitute from less than 5% to over 20% of the total volume of the microstructure of the steel. The actual hardness of individual carbide particles depends on their chemical composition. Chromium carbides are about 65/70 HRC, molybdenum and tungsten carbides are about 75 HRC, and vanadium carbides are 80/85 HRC.
These embedded carbide particles function like the cobblestones in a cobblestone street. They are harder than the steel matrix around them, and can help prevent the matrix from being worn away in service. The amount and type of carbide present in a particular grade of steel is largely responsible for differences in wear resistance. At similar hardnesses, steels with greater amounts of carbides or carbides of a higher hardness, will show better resistance to wear. This factor accounts for differences in wear resistance among, say, O1, A2, D2, and M4. Ideally, tool steels would contain as much carbide volume as needed for the desired wear performance. In fact solid carbide tooling is typically 85% or 90% tungsten carbide particles, in a matrix of 10% or 15% cobalt to hold them together. Chemically, the microscopic carbide particles in tool steels are similar to the carbide particles in solid carbide tools. However, very high amounts of carbide particles can lead to problems in grinding, or lower toughness.
Hardness of Carbides
Alloy elements (Cr, V, W, Mo) form hard carbide particles in tool steel microstructures.
The amount and type present influence the wear resistance.
HARDENED STEEL 60/65 HRC
CHROMIUM CARBIDES 66/68 HRC
MOLYBDENUM CARBIDES 72/77 HRC
TUNGSTEN CARBIDES 72/77 HRC
VANADIUM CARBIDES 82/84 HRC
Tool steels contain the element carbon, in levels from about 0.5% up to over 2%. The minimum level of about 0.5% is required to allow the steels to harden to the 60 HRC level during heat treating. The excess carbon above 0.5% plays little role in the hardening of the steels. Instead, it is intended to combine with other elements in the steel to form hard particles called carbides. Tool steels contain elements such as chromium, molybdenum, tungsten, and vanadium. These elements combine with the excess carbon to form chromium carbides, tungsten carbides, vanadium carbides, etc. These carbide particles are microscopic in size, and constitute from less than 5% to over 20% of the total volume of the microstructure of the steel. The actual hardness of individual carbide particles depends on their chemical composition. Chromium carbides are about 65/70 HRC, molybdenum and tungsten carbides are about 75 HRC, and vanadium carbides are 80/85 HRC.
These embedded carbide particles function like the cobblestones in a cobblestone street. They are harder than the steel matrix around them, and can help prevent the matrix from being worn away in service. The amount and type of carbide present in a particular grade of steel is largely responsible for differences in wear resistance. At similar hardnesses, steels with greater amounts of carbides or carbides of a higher hardness, will show better resistance to wear. This factor accounts for differences in wear resistance among, say, O1, A2, D2, and M4. Ideally, tool steels would contain as much carbide volume as needed for the desired wear performance. In fact solid carbide tooling is typically 85% or 90% tungsten carbide particles, in a matrix of 10% or 15% cobalt to hold them together. Chemically, the microscopic carbide particles in tool steels are similar to the carbide particles in solid carbide tools. However, very high amounts of carbide particles can lead to problems in grinding, or lower toughness.