VG-10 is my favorite stainless. CPM 440V is one of my least favorite.
VG-10 takes a wicked sharp edge pretty easily. CPM 440V was difficult for me to get as sharp as I like knives to be, at least for a polished, push-cutting type edge. It does take a rough, slicing edge and holds it a long time if you are cutting abrasive materials. It doesn't perform so well if there is any signifigant edge impacting going on.
I have DMT hones and a Spyderco Sharpmaker and several other sharpening devices, and I had a lot of trouble getting the kind of shaving edge I like with the 440V.
I have no trouble with VG-10.
Both are premium steels; VG-10 just suits my personal preferences better. It acts more like a carbon steel to me.