Knife making rookie. Long time window industry worker.
Architectural glass is made by pouring molten glass into a giant vat of molten tin. The glass floats on the tin like grease on water. The end of the vat furthest from the glass furnace is cool enough for the glass to solidify, but the tin remains liquid. So sheet glass with a very high degree of flatness rolls continuously off that end of the vat. Amazing process to see.
A couple of points;
-how flat is "flat"? I don't have specs on how flat architectural glass really is; the objective is to produce a product with no or minimal visible ripples. For sharpening woodworking tools, I'd say plate glass is plenty flat enough. But I wouldn't suggest that a machinist/toolmaker would be satisfied with glass as a substitute for a proper granite surface plate that might have a 0.0001" tolerance.
-the glass has to be thick enough to be rigid. You can get glass (or sheet metal, for another example) that is very flat, but is not capable of supporting its own weight without flexing. That's at least part of the reason real surface plates are as thick as they are. Inherent flatness is beside the point if the material is so thin that it conforms to the surface you lay it on. Just guessing, I would think that 3/8" would do pretty well for a 2ft by 2ft piece of glass. 1/2" would be better.
-avoid tempered (heat treated) safety glass. Heat treated sheet glass like what is used in windows inevitably gets ripples in it from the heat treatment process. It isn't a desirable feature in window glass, but if tempered glass is necessary, ripples are considered normal. Now, I'll point out that the deviation in flatness required to cause a visible ripple is very small, but in any case annealed glass will be flatter than tempered.
-I don't know what flatness standard granite countertops are made to either. I have a sink cutout in my basement, and it is flat enough to suit any woodworking / tool sharpening need that I have had. But again, it probably is no comparison to what Starrett would sell you.
So, just how flat do you need it to be, and how tight is your budget?
If getting something as flat enough that you can't find defects with a quality straightedge and a feeler gauge is good enough, then you can probably take your straightedge and feeler gauge to a counter shop or a glass shop and get what you need cheap.
If you want something really FLAT, then you can get an actual made to the purpose surface plate for a couple of hundred dollars or less, depending upon whether there is a local source where you can pick it up (even a small one is pretty heavy. so freight charges could be a factor)