HELP! epoxy / G-10 adhesion problem!

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Nov 14, 2017
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I'm using G-10 for liners. I'm gluing up wood scales with a bolster of either buffalo horn or ebony. Several times now, as I've been trying to assemble things for final glue-up, or doing sanding, or whatever -- the G-10's peeled RIGHT off the #*&(@! scales/bolsters.

I'm using BSI (Bob Smith Industries) 15-min epoxy, which is their most flexible stuff (I think that's good), with a full 24h cure (in a nice warm room btw). I've used several woods: redwood burl, thuya, sindora. They've all been stabilized - the redwood by me using Cactus Juice; the others commercially. I've cleaned/degreased and roughed up both the G-10 and the scales. (I've probably used several different methods of cleaning/degreasing, btw - I tend to use generic dishwashing liquid, and/or IPA...)

ANY thoughts? Should I switch to West GFlex? (I've had GREAT results w/ BSI epoxy other'n with G-10...)

Thanks!
Andrew
 
(Update: just found extensive info under "Glue Wars". Read through it. MUCH good info, but didn't quite address adhesion to G-10 - I think?!? - and definitely not anything re: BSI epoxy - so still hoping for info, T.I.A.!)
 
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I use the 24 hour cure epoxy from West Marine, no issues with adhesion. my understanding is that the 15 min stuff is.....inadequate.
 
Are you roughing up the G-10 before glueing?

~Chip
 
I use the 24 hour cure epoxy from West Marine, no issues with adhesion. my understanding is that the 15 min stuff is.....inadequate.
This is correct. I believe West Marine stuff is either 20% or 50% off right now, so grab it if you can.

Aside from that, what are you using to clean the surfaces? You should use denatured alcohol as your final pass, to not leave a residue. Acetone can leave a residue that may affect adhesion.
 
I use BSI 30 minute. It is the best for knifemaking of the BSI line. I tried the 15 minute and it was not as good.
 
Sand both surfaces with 50 grit and use only enough pressure to get the materials to lay flat. Use DN alcohol as mentioned.

We often use to much pressure and squeeze out the glue.

Also dont use the 15 minute stuff, the 30 min stuff is the strongest they make.
 
Have you considered that you might have something other than G10? If you have a thermo plastic rather than a thermo set plastic, most glues own't stick to it.
Just a thought.
Jim
 
Sand both surfaces with 50 grit and use only enough pressure to get the materials to lay flat. Use DN alcohol as mentioned.

We often use to much pressure and squeeze out the glue.

Also dont use the 15 minute stuff, the 30 min stuff is the strongest they make.

I bet this is the problem. Epoxy needs a layer between the items you're gluing together about as thick as a piece of paper. If you squeeze too hard, then you squeeze out too much epoxy and end up with a glue starved joint that is weak.

I've used the BSI 30 minute epoxy to glue G10 to brass, copper, natural wood, stabilized wood, and steel without issues.
 
I bet this is the problem. Epoxy needs a layer between the items you're gluing together about as thick as a piece of paper. If you squeeze too hard, then you squeeze out too much epoxy and end up with a glue starved joint that is weak.

I've used the BSI 30 minute epoxy to glue G10 to brass, copper, natural wood, stabilized wood, and steel without issues.

I don t think that it is the problem . . . When you sand both surfaces with 50 grit you increase surface /square inches / on piece you want to glue .Of course that mind stronger joint .If you don t sand surface joint will be weaker / because smaller surface / but will GLUE ! How I can glue two piece of glass ? Same if you squeeze out to much , you cant squeeze ALL epoxy .Reminder ........ a thin layer of epoxy between the two piece we gluing is stronger then thicker one.........;)

PS .Take two small piece of glass ,mix some epoxy then put on both piece of glass ,joint them and try as much hard you can to squeeze ALL epoxy and tell us what happened .
 
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I would be willing to bet that the issue is a glue starved joint. I bet you assembled the pieces and clamped the heck out of them. This squeezed all the resin out from between the pieces.
There was no glue left in the joint and the pieces just peeled/popped apart. Take Adam's advice about very rough sanding ... and very light clamping.

I use the smallest and cheapest spring clamps from HF. They have just enough power to hold things in place. Screw clamps are the worst to use. They can apply tons of pressure.
 
I would be willing to bet that the issue is a glue starved joint. I bet you assembled the pieces and clamped the heck out of them. This squeezed all the resin out from between the pieces.
For maximum bond strength leave a minimum of .007" epoxy. I got this information directly from West System.

Chuck
 
Wow! Lots of great responses. I'll summarize and respond, but first I just recalled - with a Homer Simpson "doh!" forehead-slap - something from my past life that might be helpful - sorry that it's long.

In my latter waste-to-fuel venture company, I was designing a microreactor that required bonding high-temp inert tubing to high-temp ("pyrex"-type) glass - which is already a challenge, but guess what the tubing was? Teflon. Everyone's heard of the ol' "so how do they get Teflon to stick to the pan?". Basically, you don't. It isn't "stuck", it's "locked", mechanically. So we're sticking Teflon to glass - fun, huh? We were using a technique* from a team at Lehigh: the glass was etched with a diamond hole-saw, and the Teflon was micro-'etched' with a funky fluoro- compound. That created a much larger, very ragged irregular surface area at the micro-level, "increasing bondability and co-efficient of friction" according to the FluoroEtch datasheet. We then used Duralco 4460 high-temp, low-viscosity, low-shrinkage epoxy from CoTronics. So, basically, the epoxy wasn't really so much "stuck" to the Teflon, as it was like having a too-small threaded bolt in a threaded hole, with a really sticky strong gap filler locking them together. Key is obviously just surface roughness/surface area; also clean surface prep so there was good bonding to the glass. Seems pretty analogous, now. So, that said, here're your thoughts & my responses.

- Glue Starvation. By far the most common suggestion. Natlek, I liked your point about "just try to squeeze all the glue out from 2 pieces of glass", although I do think you can starve a joint somewhat (and Chuck's from-the-horse's-mouth advice from West is useful, so might try measuring the thickness Δ for fun). Btw Stacy, I'm using spring clamps from Home Depot ("Durabuilt") which are maybe stronger than HF's but don't seem to be getting a ton of squeezeout - I agree Jorgenson's or other screw clamps would be too much.
- Roughing/Properly Cleaning the G10. Yep, Chip, Bill & Adam - I've done that, using a 60 grit and good pressure until I got a good scuffed surface. I think I'll try even more scuffing and try to expose a surface that's mostly fiberglass mat. I've seen suggestions elsewhere to drill some little holes through the G10 into the scales which seems helpful although I hope overkill 'cause that's lots of extra work (and risk of drill-through) and others don't seem to need to do it.... And yes I definitely do final cleanup with IPA, not acetone now - I know about the oily film**. Curious: does anyone have a strong opinion about "DN" vs. IPA? And by DN are we talking EtOH w/ a denaturant or MeOH (either meets the def'n at least in the lab). And if so do y'all use 70%, or Heet yellow (which is almost all MeOH btw), or what
- Choice of Epoxy Interesting. Kevin, I could've sworn that BSI said their 15-min is the strongest (IIRC) and also most flexible, which seems like a good characteristic. Edit: just checked BSI site. 15-min is most flexible, but 30-min is strongest. It's also apparently better for metal/glass bonding; while 15-min is preferred for hardwood that's obviously less interesting. The 30-min has handle time of 8h and full-cure in 24h, vs 45m/2h for the 15m. That said: I'm hearing a strong preference for West Systems G/Flex. (Bill, thx for the pointer that it might be on sale - is that at the stores? I looked on the website, don't see a sale on it...?) It costs about 2x vs. BSI - but per-knife who cares about say 30¢...?
- Is it Really G10? Yep, Jim, bought it from TruGrit, just double-checked my order for belt-and-suspenders, but good "are you sure it's plugged in?" thought.

My own add'l thoughts: I should re-make sure I'm really mixing it thoroughly, and in the right proportion. I am using handle pins (plain, not Corby/Loveless), and this is for exotic-wood chefs' knives, not outdoor rough-use. I tend to believe that the pins make sure any shearing force can't get too strong, and it's hard to imagine any 'pulling' force on the scales let alone 'prying' action, so the epoxy ultimately shouldn't have much mechanical stress on it. As long as it's fairly strong and stays adhered, and is waterproof -- and I tell my customers if they get their wood soaked, even though I do stabilize it, they're not only way out-of-warranty but also undeserving Visigoths -- and if it gets soaked enough to hurt epoxy they've got worse problems with the wood and the 80CrV2, anyhow. :) That said, I think switching to G/Flex is good insurance. Sorta like the (very old) saying in the 'puter industry: nobody ever got fired for buying Microsoft.

Thanks again, all. BF is a wonderful community.
Andrew

*(here's a link; I have the full paper w/ pix and detail if anyone's interested)
**(from that past life I happen to have a patent in hydrocarbon chemistry so that's something I get well.)
 
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Sounds like you may have it solved. I was part of the glue wars testing so I'll throw in my two cents FWIW. (There is also an old thread on Knife Center related to the glue wars thread here. They were supposed to mirror each other but ended up splitting apart. Disclaimer: I sell adhesives but this testing was done before I got into supply sales. Chuck at Alpha supply donated some wood and metal for the testing back then. Thanks to Chuck. )

Using soap to prep a surface caused failure consistently. Using Acetone to clean also caused problems. Not roughing up both surfaces enough caused failures. I use 90% rubbing alcohol to clean a surface. Glue joint starvation also showed up as an issue.

Manufactures use sand blasted coupons to test and rate their adhesives. That should tell you most of what you want to know for surface prep.

"marginal" adhesives outperformed the "best" adhesives simply based on surface prep.
 
I will add:
Most folks worry that a very rough sanded surface will show a big gap between the scales and tang after the glue-up. There is little chance of that unless the surface is not flat.

A surface sanded at 50 grit looks very rough, but only has grooves that are around .013" wide. So, where two grooves are opposed on surfaces that are ground on 50 grit belts, the epoxy depth can reach a max of .026". That is the thickest, the average is half that ... or .013".
10o grit averages .008" resin thickness.
220 grit finish average resin thickness is .004" ( This is the thickness of a sheet of printer paper.)
400 grit average resin thickness is .002"
Thus, using Chuck's .007" as the minimum resin thickness for bonding, you have to sand the materials on a flat surface at 100 grit or less to get a suitable bond. A 400 grit surface, which is common in people trying to get "Everything perfectly flat", is far too smooth for a proper resin bond.

I use a 50 grit belt and a flat platen. I touch it up on a granite plate with 100 grit paper to assure flatness.
This assures good grooves for the epoxy to bed in.
 
@stacy ,I agree with everything you advice here .That s the right way to glue scale on tang . I do it as you say , but you can sand scale up to 20000 grit if you want and put two part you gluing in hydraulic press if you want and epoxy would GLUE .It wont be strongest joint on world but will not be easy to part ..........Epoxy is liquid and very sticky and simple you can not squeeze out all ...........
 
I'm using G-10 for liners. I'm gluing up wood scales with a bolster of either buffalo horn or ebony. Several times now, as I've been trying to assemble things for final glue-up, or doing sanding, or whatever -- the G-10's peeled RIGHT off the #*&(@! scales/bolsters.

I'm using BSI (Bob Smith Industries) 15-min epoxy, which is their most flexible stuff (I think that's good), with a full 24h cure (in a nice warm room btw). I've used several woods: redwood burl, thuya, sindora. They've all been stabilized - the redwood by me using Cactus Juice; the others commercially. I've cleaned/degreased and roughed up both the G-10 and the scales. (I've probably used several different methods of cleaning/degreasing, btw - I tend to use generic dishwashing liquid, and/or IPA...)

ANY thoughts? Should I switch to West GFlex? (I've had GREAT results w/ BSI epoxy other'n with G-10...)

Thanks!
Andrew
Did epoxy hardened ? Once It s happened to me with one laminated scale /G10 with layer of fabric like on micarta on surface on both side/ ........Epoxy hardened on steel but don t on that scale ...months after that that scale is still sticky ............I suppose that the reason /maybe / is release agent soak in that thin layer of fabric ??
 
When I started making knives I clamped like I always have clamped when woodworking and I had some problems with squeezing the epoxy out of the joint and the joint failures (I believe it can happen). Switched to lighter clamps made a big improvement for me. I bought some spring clamps from ebay that was like 10.00 for 100 shipped from china. I would not have been happy with the clamps if for woodworking but they were perfect for this.

Just a thought- some epoxy uses a different ratio if mixing by weight or volume
 
Another tip is to drill pockets from the g10 liners into a small portion of the handle material. This will create epoxy"pins"
 
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