For heating, take find out what type of Bolt you got and go here
http://www.boltaron.com/films/listing.asp
Sonil is right, bolt curls and kydex shrinks, I use both and hate them both equally at the moment.
As for heating techniques, start with a low temp, let soak, and ramp it up in steps... remember to get your oven to the desired temp your elements are going to get HOTTER than what you want.
Go slow with this until you get to know how your oven works.
If you're going to sandwich your material, put a paper towel on either side of it... should prevent the material burning...
Use an IR or non contact thermometer to get the temp of your material... don't use the temp gage on your oven (that measures the ambient temp of the cooking space.
If the data sheet says your optimum temp is 350... get it as close to that as possible, DO NOT go over it.
Now if I could only practice what I preach lol
BTW this advice goes for both Kydex and Boltaron... they're both thermal form plastics...
Another thing, you'll see around the threads that people will "heat until pliable". This is good, but since you're talking about going to the "higher" temps it sounds to me like you're going after "high definition" presses.
The "forming temperature" for
boltaron 4335 is 335 - 370°F / 168 - 185°C, This is the stuff sold at usa knife maker dot com