S30V is truly a "next generation" steel. It is based on powdered metallurgy technology and was designed specifically for cutlery applications. It has a terrific balance of properties and outshines VG-10 by a big margin. Notice that I said "balance of properties" which correctly infers that some other steels may outperform it in specific applications.
An example would be to compare Talonite (a cobalt alloy, not a steel) with S30V. A Talonite blade is impervious to corrosion; it could be used around salt water or in butchering and skinning where it might be left in contact with blood, etc. for long periods of time, and NOT show the slightest corrosion. Although S30V has excellent corrosion resistance, Talonite would outperform it for ultimate corrosion resistance.
Yet Talonite has only half the strength of S30V. You can put a nasty notch in it hitting a staple while cutting cardboard or significantly damage the edge by attempting heavy work around hard wood or even bones. And an attempt to cut your way through a car door in an emergency would be ludicrous. S30V would dominate in these areas.
That said, only a few per cent of buyers will use their blades to the level that any significant difference will be noticed. Additionally, many other factors, such as the grind, the shape of the blade, and the heat treatment will have at least as much, if not more, effect on the knife's performance than will the choice of VG-10 vs. S30V.
So, Steve, you're probably not going to notice much difference between the steels. Both perform very well in a properly designed blade.