SkaerE,
I'll try and explain better, but remember I haven't tried this thing out yet, except with salt water. It etches! I can tell you that much.
FYI: Here's one from Bob Warner that gave me the idea:
http://www.warnerknives.com/electro.htm
rlinger mentioned 24 volts. The Lectro-chem and other machines are 12 volts 3 amps. So, I think we're ok with that. Variable DC would be nice too, but right off the power supply we get 5 volts too.
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OK Here's what I know:
What you're after is 12vdc and 12vac. The PC power supply has a whole bunch of wires spuing out with connectors for hard drives and such. Those are your DC power leads. (The connectors with more wires are for the motherboard, you don't need those.) You'll want a black wire for negative and the yellow (double check with a volt meter) for 12 positive. Then a red wire is probably going to be your 5 volt positive. Cut all the rest of the wires off. So, the only things coming out of the case are 3 wires: black, red, and yellow.
If you plug in the power supply and flip the switch on it, you can prove that out. As long as you don't open the case you're pretty safe. Nothing worse than a car battery.
The next part has some risk and requires an AC volt meter. Proceed at your own risk!
Unplug and remove to the cover on the supply and unbolt the circuit board. Look it over. There'll be a big transformer on it. There are wires going into it on both sides. Turn the circuit board over and find the leads going in and out of the transformer.
Here comes some more risk, no big deal if you've played with this stuff before.
Make sure the upside down circuit board isn't resting on any metal to short out and plug the thing in. Turn it on. Lights still on in the house? Good.
With a volt meter set to AC, test 2 leads on one side of the transformer. You should see either 120VAC or 12ish. Once you find the 2 leads with 12 volts you're home free.
Unplug it.
Now solder a wire on each lead and you have your 12VAC! Stick the wires back thru the case and put it back together.
Which wire is which doesn't matter on AC.
I'll probably buy some switches like Bob has and mount them in the case.
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I don't know how well this works and if the DC current is clean enough for a good etch. But heck the parts are free and worth a try.
I hope that helps.
Steve