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Try backing off the pivot tension.
Loosen it to the point that you'd be afraid of losing the pivot screw, then tighten it back up to where it barely seats on the Ti.
If you're afraid of losing the pivot screw, put a little Loctite on the threads to keep it in place.
If it's new, it will take a break in period for the knife to be smoother and a callous build up on your thumb.
There is a specific technique TO opening a CRK.