Multiple quench and multiple tempering are two different things.
Multiple quench: Take the steel just past critical and quench. Do it again, and now again. Some swear by it when done properly, others who are serious about their metallurgy say it makes no sense at all. There is a long thread about it still floating around this forum right now. It is used with 5160 and 52100.
Multiple temper: After your quench heat the steel to 350f - 450f ( or so depending on the steel ) for one to two hours. Let it cool to room temp and repeat. Some do it a third time. This makes sure that all Matrinsite gets tempered, even some that may have formed during the previous cycle. Pretty much everyone agrees this is a good idea on any steel.
Seth