Right now I'm only able to get one unfortunately. But would the DMT be good for touch ups with the fine/extra fine diafold?
That'll handle touch-ups easily. Either with the guide, or freehand if/when you wish to pursue that down the road. If you do use the Aligner or Magna-Guide (for Dia-Folds), I would recommend a coarse or XC hone also, if you ever need to do some heavier grinding or re-bevelling.
Both of the systems are useful, for completely different reasons. But I do believe the DMT system is more versatile overall.
The DMT system, as mentioned, is much better for re-bevelling jobs, for several reasons. First, diamond hones will remove steel much more quickly than the ceramics of the Sharpmaker. This becomes hugely apparent, the bigger and thicker the blade becomes. The second advantage is the guide, which obviously makes re-setting a bevel on a blade much more consistent and accurate. The third advantage is the availability of a full range of grit choices in the hones, from XC through EEF. A fourth advantage is a great one: the clamp can be used with any bench hone as well, so you're not limited to just the dedicated hones with the Aligner/Magna-Guide system.
The Sharpmaker is great,
after the blade has a good bevel on it. For daily/occasional touch-ups, it's about as easy & convenient a system you'll ever find. The downside to using ceramics, on any system, is that they won't remove steel quickly, and extended sharpening sessions will load up the ceramic with steel swarf, which makes them even less aggressive. For this reason, it's much more important to make sure the ceramic stays relatively clean. There are some diamond 'sleeves' available for the Sharpmaker, which add some aggressiveness. But, it's just the one grit choice, and it's still relatively 'fine' as compared to other diamond hones. They're also pretty expensive, for what you get. IF you don't have any plans to do heavy re-bevelling on your knives, and if they already have some decent bevels on them, the Sharpmaker might be all you'll need. That's provided you don't fall behind on touch-ups and let them get too dull, after which you'll begin to notice the limitations of the system.