It would all be so easy if things would just work in a way that we would like them to :grumpy: . One of the problems is that the iron-carbon equilibrium diagram is only good under equlilibrium conditions. Rate of heating will heavily influence the Ac temps and alloying elements will really move things around. We have a discussion going over on the SFI metallurgical forum about how alloying pushes the eutectoid point to lord knows where.
The curie temperature could be a full blown discussion unto itself and presents many conundrums and paradoxes that leave me scratching my head. But it does appear to be a point that is more constant than the other points of the Fe-FeC3 diagram. The Curie point of iron does appear to be 1414F. (at least until you reach Delta iron- one of those head scrathing things) which makes it a good guide to get you in the neighborhood, you then need to adjust for how much more carbon or ferrite you may need to dissolve. The best way to play it is if you are not over heating things let the tmperature do its thing and soak it.
Just remember that the non magnetic thing is only good for a ball park on the rising heat. Heat a piece of steel to non magnetic and then let it cool while testing with the magnet, then tell me if you would EVER quench a pice of steel at the color that the magnet finally started sticking again

Ac and Ar are not the same