Depending on what they mean by a 25° angle (per side or inclusive), that figure may or may not be a good starting point. If they mean 25° per side (50° inclusive), that's an extremely wide edge and it won't cut very well - or maybe not at all - when the apex dulls even slightly. And whichever angle is best also depends on what uses your knife will be put to.
For my own typical uses with my pocket knives, I like something in the 25° inclusive ballpark (that would be 12.5° per side). Great slicing geometry, so long as the blade isn't subjected to unusually hard use, like heavy chopping or twisting during cutting, etc., all of which can severely deform or chip a thin edge. Anything around 30° inclusive (15°/side) will cut pretty well and is usually safe for most any blade, so long as it's not subjected to very hard use. That's usually a decent starting point, after which you can see how it holds up and then decide if you want to take it narrower or a bit wider, for the sake of balancing cutting performance against the need for frequent repair or heavy resharpening to keep it cutting well.