Well, first of all it is important to distinguish between carbide and grain size...which I didn't do in my first post either...I appolgize. Most stainless and high carbon steels are sintered these days, even those that are not CPM steels. During the sintering process to obtain maximum performance from the steel, maximum grain growth and desification is usually a wanted property. Again, there are exeptions, especially if a porus structure is wanted (like gray/porus, white/closed pores sharpmaker rods). The grain structure is also affected during the heat treat and cryogenic cooling. The carbide size is the aggregation of the carbides within the steel and usually a well dispersed small carbide structure is wanted. Having said that, I don't know, which of the common steels have which structures.
Jeff, I totally share your experience. My housemate has a few knives that hold a sentimental value to him, and I hate them because the steel is so poor that you can't get an edge no matter what, but I doubed that that is due to grain size. Even among the steels that is mostly talked about on this forum I find that I am not a fan of 420HC because the in my experience the edge rolles way too easily, even during shapening, while I find that only Shirogami (white paper steel) takes an edge as easily and keeps it, as the A2 knife from Bark River I recently got, even though both steels are hardened to a much different degree. So there is definitely a difference. But also from experience I must say that I see a significant improvement in an edge finished on a 6000-10000 grit stone over one that is finished on a 3000 grit, whether the steel may be ATS-34/55, A2, CPM30V or VG-10. But I don't play around with angles too much, I sharpen most of my knives to 30 deg included, with some that see abuse at 40 deg.
But that's only my $0.02.
Duh, I should have read Cliff's last post :footinmou. I read the same thing about the woodworkers...but I would like to point out that there definition of polished edges is quite amazing. They are arguing over whether or not you should go from 5000 grit to 8000 grit or to 15000 or even 30000 grit

.
Richard: try "Sintering Theory and Practice" by Randall German. It doesn't say much about heat treating but a lot about activated solid state sintering used for many high carbon steels, and liquid sintering used for many carbides and stainless steels. But it doesn't talk about specific steels. I wouldn't be surprised if that information would be hard to come by as it is proprietary.