I definitely do NOT want to drift this into some HT controversy thread, much of it seems to surround 52100. Just wanted to dig up a bit more from a different perspective. I'm still looking for the objective science out there.
Some, like Mister C, says that the triple quench may had been devised to fix what people had messed up in the forging and rudimentary heat treat and make sure your converted everything to martensite.
-Joe Mandt
Joe, I do have enormous respect for Mr. C., and I'm sure in many cases what you mention is the primary benefit. I'm not at all sure though that the rewards stop there, if you know what you're shooting for with 52100.
Pasted from elsewhere on the web:
The theory behind the triple quench is that by bringing the blade rapidly up to the hardening temperature, the grain size remains smaller then when the usual soak time is used. The soak time allows all the transformations to be made within the steel, yet the grain grows with the additional time at the soak temperature. With the rapid quench the transformation is not complete, however the second and third quenches complete the necessary transformation.
Not sure who said that, possibly E.F... and I definitely don't subscribe to everything else that goes with it from those guys. But, it does make sense to me, and I do 3-quench my 52100. I do evenly heat the entire blade, and oven temper twice, then soften the back with a torch.
I've recently tried single quenching several 52100 blades in P50, then giving them the same tempering regimen as my other 52100. I've not finished them out yet for cut testing, I'm interested to see what the difference may be.
I've seen results of an experiment posted where the OP deliberately overheated the steel to increase grain size, then tested single and multiple quenching, successfully reducing grain size more significantly with triple quenching. That's informative, but not satisfying to me, as the steel had been overheated. I'd like to see the results of the two quench methods compared on 52100 never brought above the correct temp. Anyone aware of such a test having been done? Like, with a salt pot or kiln, not a torch?