I regularly store knives in polymer sheaths. No problems. If they're going to be stored for an extended period of time, I do give the blades a quick wipe with a Tuff Cloth if one is handy, or if not WD-40, CLP, silicone cloth etc.
The polymers do not absorb moisture and since they are not cured, there are no issues with acids leaching out of the material and damaging the blade.
Vegetable tanned leather will not leak nasties on your blade either. (I was educated by Leatherman on that little tidbit).