Theres a lot of info on s90v. Check the maintenance sub-forum, the spyderco sub-forum here and the Spyderco Forum. Spyderco has put out most of the s90v so thats where you'll find the most info. I've never used it myself but I use a lot of s30v and have knives in both s60v and s110v, both of which perform amazingly for my useage. The s60v I have has amazing wear resistance but is run pretty soft because s60v is not the toughest steel out there. As a result it loses its hair poppin edge fairly quickly but will hold a sharp work edge forever. I have not used the s110v a whole lot but from the light use its seen and what I have read it should have incredible wear resistance yet take a bit longer to sharpen.
The S**v crucible steels are very good american steels that work extremely well on working knives where a super fine crisp hair poppin edge isn't very important, but rather a good cutting edge that you don't have to sharpen often. If you need something that holds a hair poppin edge for as long as possibly you might look elsewhere, I've got knives in ZDP-189 and CPM-M4 that are better in that aspect. It really all depends on what you want in a blade. There has been a lot of excellent discussion lately in the maintenace sub forum here.