I do like S30V better than VG-10, and I do have the S30V Native. It is a very good cutter, and it holds its edge very well. S30V is probably my favorite steel, although steel is not a deal breaker for me.
You should really hold the knife before you go out and buy it, though. The Native's grip requires that you use the choil. Personally, I quite dislike choils, and if you don't use the choil on the Native, it is very uncomfortable to use. Also, I dislike the lack of liners.
If the Native had liners + screw construction and a better handle shape, it would definitely be one of my "ultimate knives."
It's a great knife, though; I'm sure you'll be very happy with it.