Jeez; a lot of good information here, but there are, unfortunately, some mistakes.
First, tritium DOES occur naturally. Here is some basic info about tritium and its' origin from MSN-Encarta :
Tritium, radioactive hydrogen isotope of atomic mass 3 and symbol 1H3 or T. The nucleus of a tritium atom consists of a proton and two neutrons and has a mass of 3.016049. It undergoes decay by beta emission to give a helium nucleus of mass 3; it has a half-life of 12.26 years. Tritium is produced in a number of ways, including the bombardment of deuterium compounds with high-energy deuterons and by the absorption of neutrons by the lithium isotope of mass 6.
Some tritium is produced in the upper levels of the atmosphere by the bombardment of nitrogen with energetic neutrons produced by cosmic rays; rainwater is usually found to contain minute amounts of tritium.
Since the low energy beta radiation of tritium cannot penetrate skin, the only harmful effects occur when it is inhaled or ingested. Inhaled tritium is rapidly exhaled; 0.004% is all that remains of an inhaled dose after one minute. Ingestion is a problem only with massive exposure; the only ill effects were seen in atomic bomb victims in Japan. Some teenagers in NJ opened some vials of tritium from an exit sign; their exposure was slight, and no ill effects occured. Here is the reference:
http://usgovinfo.about.com/newsissues/usgovinfo/library/news/aa060500a.htm?iam=dpile&terms=Tritium+Sight
The tritium in night sights is in the form of tritium oxide, or water made with tritium. This is because elemental tritium diffuses well and would probably go through the glass tube in a short time. Remember that hydrogen will diffuse through solid palladium metal. The tritium in a night sight follows the water pathway through the body; thus it is excreted rapidly.
An intact night sight offers no health hazard. Remember that the tritium oxide inside the glass vial excites phosphors in the solution; it is the light from this process which passes through the glass. Virtually no beta radiation would penetrate the glass, and that which did would certainly not penetrate your skin.
Unfortunately, the stuff that you would need for an auto is tritium paint. As far as I know, this is restricted to manufacturers who have licenses to handle radioactive materials.
Hope this helps. Walt
[This message has been edited by Walt Welch (edited 07-09-2000).]