Two things will greatly impact how easily the SM can sharpen the S30V Sebenza: First, if it's very dull, with a long time since new or last fully-sharpened, and (second) the S30V will make that task much more difficult if it is very dull. If it is, diamond is the best way to get a workable bevel on it again. Once that's in place, the medium rods can add some nice bite. That's where I've chosen to leave off, when touching up two Sebenzas I have. I don't have the diamond sleeves for the SM, but have used a Fine/EF DMT 'credit card' to do the work that's been a little more difficult for the SM's ceramic rods to do alone. The Sebenza does have a (very) subtle convex from the factory, but it's nothing that'll get in the way of the Sharpmaker or any other V-bevel sharpening method. At the time I bought my Sebenzas, I'm pretty sure Chris Reeve was even recommending the Sharpmaker as an efficient tool to maintain the edges on them (again, so long as it doesn't fall too far behind in upkeep).
David