This has been my experience as well.I like the 20CV Hinderer I have quite a bit, but when it comes to the only knives I have by the same company made in both steels (Spyderco) I strongly prefer their S90V. It's not something I can really quantify, just a feeling when I'm using it that has left me impressed with the steel. It's almost similar to the way I feel about Spyderco's K390, but in a stainless; I just know I like using it. Whereas when I'm using Spyderco's 20CV I always get the feeling like it wants to chip if pushed too hard. Other's mileage may vary, and I offer no expertise here, just a layman's experience using both steels.
Between these two choices, I would go with S90V.