Deep Cyro Processing of 52100 Test Results

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Nov 17, 2008
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Fellow knifemakers,

As per my commitment to share my test results Im doing so in this post. Please note, I'm not interested in any personalities, egos, irrational discussions or fanciful interpretations of what I am saying. You wont get any responses from me on those sorts of comments.

FULL DISCLOSURE: I do not make any money from my knives - in fact it costs me money. Its a hobby I find therapeutic and fun. I have no commercial interest in knives or related services. I am an engineering consultant where I an run an independent services business to industry. I was initially looking at a 3 week wait for the shop to do the processing. I have a client who uses the shop with big dollar orders and was able to leverage priority for all my orders at normal prices. The shop did not know there was any testing to be done, it was simply a routine order for them processing "parts". I consider myself to be an honest and ethical man, and I certify everything in this report is true and correct to the best of my knowledge.

FACTS IN DEEP CYRO TREATMENT:

Scientific research has shown in some materials a:

* Conversion of retained austentite to martensite
* Enhanced precipitation of small carbides
* Small increase in hardness
* Deep cyro provides more benefit that cyro processing

POINTS NOT FULLY SETTLED

* There is examples of something else happening with deep cyro as non steel materials are also showing some benefits as discovered in research papers by NASA.
* There has been examples that toughness may be negatively effected.
* There is examples of tool steel being easier to work post treatment
* There is examples of completed parts post tempering have greater service life

CLAIMS MADE

* Mike Stewart claims a 200 - 400 % better edge taking and edge holding.
* Busse claims a benefit but wont detail further due to his proprietary process.
* Research papers and various industry evidence have found a 420% increase in wear resistance of 52100 industrial tooling. Please note, these are not knives that we use.

PROCESS

I get my 52100 from a client/colleague who has a 100 ton press. He receives new annealed 52100 and works it into suitable blanks for me. I do stock removal, and I tend to do full flat ground drop point knives. The further processing is done at the processing shop. There it is hardened / quenched in a computer controlled industrial oven using one cycle. Of the four samples, one was not cyroed, the other three were. Immediately following quenching the profile was a slow draw down to -310F, held for 24 hours, then a slow rise until triple quenching. I do not profess this process is optimal, its simply what I had available to me.

TESTS

I was looking at CATRA tests, ASTM tests and other types and pondering how I might build a test harness to test it with. Looking at other tests conducted in the past it had received criticism that substantially different results are obtained in human hands. In the end I decided to get my son who as delighted to participate in the tests to cut nylon rope. A small wooden jig was put together to feed the rope and provide a backstop against the nylon rope. I figure that a real test with a human would best give me meaningful human performance indicators. As far as possible I instructed and observed my son perform the same type of cuts at the same angle, within reasonable human error. The blades were marked with roman numerals where only my wife knew what knives were what during the test. The cuts were stopped at the point which my son was unable to cut the rope using his fingers in the standard testing position he was using.

RESULTS

* There was no standard deviation of the blades beyond what could reasonably considered within the realm of human error in the testing.
* The deep cyro blades exhibit a 23% better edge retention. I mean that it was able to cut 23% more rope by my son in this test position on the jig.
* My results do not correlate to Mike Stewart's 200 - 400 % better edge retention. I do not know Mike Stewart's material or his process and am therefore unable to offer a fair and reasonable comment as to why the difference exists.
* An observation, not something I'm willing to state as fact right now, was that sharpening the cyro blades up afterwards seemed to me to be noticeably easier.
* I have a colleague/friend who is a metrologist and I have given the samples to him to have a look at. I hope to get some interesting metrics back from him. In particular I am interested in metrics about hardness and toughness from him.
* This is not the end of my tests its simply the beginning. Maybe it is possible to get 200% - I don't know. What I do know is there lots more inquiry to do.

I welcome people to repeat the test or do different ones, thanks.

Best Wishes.
 
Yes, that's very interesting. A 23% increase in cutting coupled with easier sharpening is intriguing - worth looking into from a simple maker's perspective.

A question. Were the blades tempered following cryo? Thanks.

Further tests on different steels would be of interest too, should anyone have the ability to perform them. I'd be happy to provide O1 test blades, since O1 is still my preferred material. ;)
 
There's a typo - "triple quenching " should be "triple tempering ".What was the retained austenite % of the two samples ?
 
Yes sorry Mete, I meant to say triple tempering, . I dont know what the situation is with single vs double vs triple tempring, its just what was a standard profile available for 52100 by the shop. They will do customer profiles by any order.

Currently I do not have any metrics but I hope to have some soon (colleague is doing metrics in his lab). I havent discussed specifically testing for retained austenite, but thats a good suggestion thanks for that.
 
maybe I missed it...what was the pre cryo hardness? post? hardness of the non cryo blade post heat treat?

also, how many test cuts for each knife before "loss" of cutting edge?
 
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this post reads much better to me

things that would still be interesting to see
1 what there heat treat profile is
2 if tweeking the profile can get you closer to the ultra high200-400% (i still have my issues with those big numbers)
3 how close to the 23% (more reasonable % increase to me ) the home smith can get with a drop into the LN tank and let soak over night (what i do now)

good post
i will try to get the harness test on the 52100 i did yesterday and post my heat treat if it came out ok
 
OK. great job. Looks like good thinking.

I wonder though if using a apparatus much like Wayne Goddard used....would result in better rersults.

I would suggest though that the arm which the blade is locked into would be a modified socket on a torque wrench? That way it could be determined at what point the amount of force used to cut whatever media increases.

Did that make sense?

As far as the 200% increase goes...it all depends on the starting point of the individual maker. If, for instance he was using an inferior HT...and then suddenly swithced to a more unifrom and complex operation....obviously he could see that dramatic change.

I can remember what Ed Fowler said to me when I started much the same type of testing in my shop...ten years ago. I will try to quote as best as memory allows. "5160 may very well show increased performance as a result of cryo treatment. But cryo really tears the guts out of 52100."

That was Ed Fowler...who has spent a lot of time...with real metallurgists...working on the same type of steel.

As for my own time with cryo...I believe one has to be extremely dedicated and extremely careful as to what claims are made because unless everything has exact repeatable scientific method applied...it all comes down to "Blonds and redheads".

Shane
 
If Stewart was referring to A2, it also tends to retain a lot of austenite, I believe. Cryo may be of more benefit in increasing hardness.

How was the sharpening easier? Was there a smaller burr, was removing the burr faster (less 'flop'), were scratches faster to remove?

The Rc numbers will be really helpful. It is a large factor in edge retention, holding others constant.
 
ok just got back form the tool and die
looks like the razor came out to Rc63 (355Ftemper)and the hunter Rc 62 (400F temper)
 
just broke the one tip off the one razor blank (it was too long anyhow)
and here are a few shots
bare with the photos as they are from a USB micro
 

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Yes I think a better test method would involve a torque wrench - thanks for that. It seems more repeatable but no so far in the direction of a CATRA test that it will be accused of not being relevant in real human use. Ill come up with something for future tests.

I dont have hardness metrics right now but my metrologist mate has the samples - I dont have pre cyro hardness values but will get the post processing values.

My spelling is awful, please ignore it my lawyer is always at me about spelling errors in contracts. (were all convicts who were banished from Britain afterall)

With easier sharpening, it seemed to be more polished and tight if thats a way to describe it. I guess it might be to do with having more small carbides? The metal just seemed to want to take a fine, clean line to it. It was easy to work which is paradoxical because I know the blades will come back with higher rockwell values. The blades were dull after testing. Im puzzled with this and will be doing tests on it.

Some points about repeating the test and the profile:

1. The industrial oven was held at 1550f. Oven is certified for aircraft and military use - very even, steady heat. Samples had a long soak time.
2. Oil quenchant at 160f. Importantly it is a very rapid quench with a computer controlled, very even rate of temp change.
3. Immediate start of cryo from quenchant temp, again all very even, no air moving around messing the temps or different temps within the chamber. The machine does not exceed more than a drop of 1f in 1 minute as it goes down.
4. -310f held for 24 hours
5. Same controlled, even and slow rise then triple tempering.
 
Hey dude....

We ain't worried about spelling...half of us...don't read all that well anyways.

I really dig what you are doing and where you are headed....

Measuring the human equation is really tough....since everybody is different....but I would suggest get a random sample individuals...do some cutting on top of a scale the way they did at the blade show in Oregon...

and then find some middle ground...

That will be about the best anybody could ask for....

besides...you are prolly way ahead of what a lot of guys do in their own shops to test their knives...

I think...in all the years I have been at it...

I tested more than one hundred blades to complete destruction.

I have only ever sold a few...and given away a few.

I have never been happy with the performance I couls wring out of either 5160...or 52100.

OK...this will be a mistake but I am going to publicly humiliate myself by releasing my "bests"

I was able to get 760 clean, full cuts from a one inch (oiled) hawser quality manila rope. This is not the macrame dry rope you see around...this is the stuff they use to secure seagoing vessels to the dock. It is some ugly stuff.

I was making cuts that went from top to bottom...and making a cut that was between 3/8" and a quarter inch long.

These were not shaving cuts that did not cover the entire diameter ofd the rope.

Because I wore my hand,wrist,arm out I devised a couple of different apparati to help with the leverage.

I know this meant that I was beyond what a human might be able to do with hand pressure. BUt I was not intereseted in anything but how long the blades would cut...until they would no longer shave hair...off my arm...dry. (not from the top...where the hair is tough and bristly...but the fuzz on the inside of the arm. A guy can tell when the thing quits biting.

As for 52100....I was able to make 980 cuts before the best blade peitered out. And by the Willow Bow School of performance that is "diddly squat".

You should really talk to Bill Burke! Man, that guy can make a blade sing, dance, make coffee, fetch a newspaper...whatever. He did some damascus that was outperfomring anything I ever dreamed about.

Bill has cut HUNDREDS of feet of manila rope. I ain't EVEN exaggerating,which I am known to do now and again.

So nobody thinks Iam a rookie maker....the blades Iam talking abuot are the ones I did start to finish...Back in the day...when I was working for another man...in his shop...I finished off a bunch of blades...swords and knives of all shapes and sizes...we did simple forged steels all the way to S7 sword blades...so I know somewhat about putting them together.

You keep at the rtesting...and keep us up on it!

I think you will be able to track the affects/effects of cryo treat pretty well as you amass more data.

Jeez..I just typed a book.

Shane
 
Nullack (since I don't know your real name, btw I'm Will)
Thank you for sharing the results of the testing. Not many makers have a CATRA machine or easy access to one.

Do you or your lab partners think that the profile may have much affect on the edge retention? Perhaps a difference in using a flat as opposed to a convex edge or differing angles?

I would hazard a guess that the 400%+ increases in industrial tooling has to do with the profiles they use compared to our blades.

Very cool information (no pun intended)... I mainly use simple steels but when I finally do get my press I'm going to play with the "fancier" blade steels.
 
I feel for one I understand the tightness and believe it is directly related to ease of sharpening. One extra step- I suppose, seems it sharpens more like cpm or Sandvik 1300
series steel after the cold. Theres a whole different world between cutting string and opening envelopes and a high performance blade on no matter what knife.Great thread and keep up the testing.
Ken.
 
Thanks Nullack, this is a great post.
I really badly wonder if a cryo-treated for example an 61 RC blade is tougher than a 61 RC blade not cryo-treated.
There is a misguidance I think about that issue, for a knife one should not compare the toughness of a for example 420 F tempered and cyro with same temp. tempered blade but not with cryo. Their RC is different. But with more RA, the same RC blade but tempered for example at 400 F maybe is not tougher than the cryo blade tempered at 420 F, maybe it is tougher (I couldn't find any conclusive experiment on this issue). This really confuses me, and for now I don't have any equipment for cryo but if toughness increases at same RC points I will definitely raise some money for that equipment. I have real big question mark on this issue. Maybe your tests can be modified for that test also ... ???
Thanks again for this experimental post... :thumbup::thumbup:
 
Yes I always appreciate a real life objective test with quality equipment over something published by some companies pet lab. Jim
 
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