Wouldn't epoxy of some kind be a stronger hold than the natural core?
Not necessarily...
OK epoxy has been around for something like 40+ years - "natural" glues have been around well... thousands of years (for instance the Iceman's aka Otzi, axe and arrowheads were all set with pitch). I've handled many knives from the 18th/19th century hafted with either pitch or the "boil it" method as well as swords/knives from as far back as circa 900 AD that were hafted with a pitch/wax mixture.
Some studies show that epoxy has a life of less than 20 years, can be affected by various solvents, heat, etc so in that sense is not necessarily better than pitch (actually rosin) based "cutler's resins".
Easier? - a matter of perception really...
For me it is not only a matter of preferring the old methods BUT it is also a matter of marketing - there is a select clientele, not huge, who will pay a craftsman to work using not only the materials, but also the methods of the "period", whether that period is 18th, 19th, 17th century or whatever. Of course as always there are those who WANT this but are unwilling to pay for it.
Is one "better" than the other - well IMO that's like asking if a knife forged in a coal forge is better than one forged in a propane forge - depends just as much on what the maker's skills are rather than the method alone.
HOW to do the "boil it" method? Jeez guys you mean you don't speak Abo (Aboman is one of the foremost authorities on all things "primitive"). Pretty much as described by Doc and Peter - drill/file a starter hole for the tang - make it at least as long but smaller in width than the tang - tapering your tang both in width and thickness helps (for those thinking that anything less than a full tang tang is "weak" - well I refer you to the tang of a Japanse Katana, which receives much more "shock" than just about any knife). BTW this works best with a core that is at least porous- although I've never used it on Sambar for instance which usually has virtually no core - I have used it with real solid deer and it bloody took forever if it all. The whole idea is by heating that porous core you change it chemically, not just soften it - basically it becomes something similar to "hide" glue which has been made from horns and hoofs as well as hides for thousands of years.
Do I use modern glues such as epoxy - you bet - when I'm being lazy (nothing negative intended) or when it MAY work faster/better than the historical materials that I prefer.