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If it is a large nodule and you want to split a blank off of it rather than shatter it.
Make a fire and put the rock next to the flames Not into[ indirect heat] when the rock is hot pull away from the fire and pour water over it.
It should split, do a practice run on an other stone first.
A way to temper flint was to bury it for a period of time this was because exposed stone was exposed to heat/cold one side.
If you want practice knapping cheap find an old toilet.
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