I use primarily 3/32" steel, and have working knives and machetes in that thickness that work wonderfully. If your knives are for slicing then I think a thinner profile would be better for beginning makers. I find that for myself and others just starting out that there is a surprising difference in grinding the two thicknesses. Plus if you leave the grind a bit too thick- as most do at early stages (myself included) the thinner overall stock would help aid in cutting efficiency.
Another thing that I would suggest is marking everything clearly on the blade blank, and go slowly, especially as you get to final dimentions. If you don't already know, do not sharpen the edge prior to heat treat, leave it about the thickness of a dime. Make sure to scribe into the edge the pre heat treat thickness, or it is easy to get a wavy edge. Start with a decent known steel of your choice (I would follow common suggestions of 1080 or 440C if you want stainless- no need to make the process more frustrating with harder to finish/grind steels). Grind approximately the same amount off of each side, switching sides every 2-3 passes on the belt or so. DO NOT USE A BENCH GRINDER WITH STONE WHEEL- you didn't say what tools you will use, draw filing the bevels can be slow, but then so will be the mistakes. What tools do you have at your disposal?
Remember that this should still be fun, you won't be perfect for a loooooong time, so don't expect a masterpiece. Get a better feel for your designs by cutting them out of cardboard/mdf/plastic or grinding out of wood-many suggest paint stir sticks for free from hardware stores.
Once you show designs/finished product here, get your thick skin out and try to leave ego behind as others rip apart your design (some with tact, some without) as most comments will be trying to help.
The first is the gateway! I started with a single knife for a friends wedding present, then did a batch of 6, and probably have 30+ at various stages of my ADD/have two young kids knife making.
Good luck and enjoy the process and the people involved! Some of the most generous people I have ever met hang around these parts! Show up for the knives, stay for the knife people! Welcome!