I haven't seen a lot of claims that ATS-34 and 154CM are better than D2. They have better corrosion resistance, sure. D2 is claimed as being "semi-stainless", and it does have greater corrosion resistance than many other alloys, but with around 5% chromium in solution after heat treatment, it is nowhere near the 10% or more that the stainless steels have. They are all high carbide steels, forming primarily chromium carbides, with around the same carbide volume. ATS-34 and 154CM have a better secondary hardening peak if you want to use an upper temper or for some reason need hot hardness. The wear resistance and edge stability are similar. ATS-34 and 154CM have a greater potential hardness, but they don't really have the toughness to work at the hardness they are capable of anyway. D2 is pretty tough considering the high carbide size and volume, but the difference between D2 and 154CM toughness-wise isn't astronomical, IMO.
When it comes to CPM-154 and S30V, the PM process gets them more into the line of toughness of D2. S30V also has greater corrosion resistance, wear resistance, and edge stability (ability to hold an acute edge). The PM process gives them a smaller average carbide size for greater toughness, corrosion resistance, potential hardness, etc. Again, S30V has similar carbide volume to these other grades, but some of it is vanadium carbide, which is even harder for greater wear resistance, but ups the difficulty on resharpening as well as finishing. The reason having a large volume of large carbides makes a steel brittle is because carbides are extremely hard and brittle, which adds to wear resistance, but have a low volume of fine, evenly dispersed carbides is much better for toughness. It's all a balance depending on the properties you want. S30V has the best balance of properites of these steels, IMO. Its main drawback is difficulty in finishing/polishing.
By the way, it can be very difficult to simply look at a composition and know the properties of a steel, not without a lot of study and knowledge of all the various balances of composition, and that is difficult without the software programs that are able to calculate it for you. Even then the software is often wrong, at least a little bit, and the real world takes over. Looking at the microstructure,\ and the various mechanical properties tells you much more about a steel. Here are a few micrographs of the steels in question, the white parts are carbides.
S30V:
http://img232.imageshack.us/my.php?image=s30vxv3.jpg
CPM-154:
http://img233.imageshack.us/my.php?image=cpm154eb3.jpg
ATS-34:
http://img232.imageshack.us/my.php?image=ats34gf2.jpg
154CM:
http://img232.imageshack.us/my.php?image=154cmll0.jpg
D2:
http://www.knifeforums.com/uploads/1181826854-D2.JPG