breakthru62,
You will really want to try the petroleum cotton balls trick. For as goofy as it sounds, it is one of the best things out there. Nearly bullet proof and works with pretty much any ignition system you have. It will even take the spark from the wheel of a dead bic lighter!
Here is how I make them. First, steal some cotton balls from your wife. She will have a tonne of these things guarenteed. They use them for make-up remover. As long as it is cotton it will be great. I like the pads better the cotton balls myself.
Now get a some vaseline. You smear a little of the vaseline onto the cotton. You don't need too much, as in gobs, just a little bit that can be spread as a thin layer along the cotton. Now you puff up some of the cotton fibres from the edge of the cotton pad or ball and aim your sparks (or flame) to hit these, these will catch the spark and transfer it to the rest of the cotton. When done right, your cotton will burn for about 40 s to a min, usually plenty of time to get your kindling going.
There are a few tricks people use to add PJCB to their kit. The problem is, you don't want your pockets lined with Vaseline

You can add them two tiny little ziplock containers. You can pack a bunch in empty 35 mm film containers. Some people like to pack them in an Altoids Mint Tine with an ignition source. Another neat trick that some people use, is they stuff them into a McDonald's drinking straw. Then you use a lighter and a pair of pliers to seal up both ends of the straw. They call this the 'fire straw'. To use it, you cut the straw open with your knife and tease out some of the cotton from between the slit of the straw. You light this on fire. The straw itself contributes to the fuel and increases the burn time. Finally, there is the method I use. I just throw some dry cotton pads in my PSK kit. I have a tiny tube (15 g or 0.5 oz) of Vaseline. They sell these small tubes for use as lip balm. I then just make up the PJCB on the fly as I need them.
Now for ignition sources. Try reading up on the firesteels, such as Light My Fire or the Doan Magnesium bar. Actually the Doan sticks can be had for about $5.00 and will produce many fires. There are a couple open threads on this right now so I will let you check them out first.
Playing with fire is, well against the expression, a whole lot of fun. Try these little tricks out. At first, just do them indoors in the kitchen with the fan on. Use a cast iron pot to start the fire in so you don't burn anything. Once you get practice at alternative igniting (i.e using firesteels and such), then start to take it outside. One you can get them to work outside, then try lighting up fires in some miserable conditions like high wind, rain and snow. It really is all about practice.
Sometimes getting a flame is the easiest thing in the world. Sometimes it is as finicky as finicky can be. Your best chance at success will be your experience and ability to try alternative methods under different conditions. Good luck - I think you will find this a lot of fun!