New video: various blade coatings tested! Cerakote, DLC, Satin, and more...

Hey mate!
So, to clarify: PVD (Physical Vapor Deposition) refers to the process that is used to apply the coating, and not the type of coating itself. For instance DLC is applied via the PVD process.

DLC (Diamond-Like Carbon) is one of the main coatings that I'm testing.

TiCN was not tested because it requires high-temperature application (~900ºF) which would ruin the heat-treatment on the knives.

-Aaron

Sorry, should've clarified. I'm basing most of what I know on the information provided by Ionbond who does the DLC for Zero Tolerance and Spyderco but I could be wrong. Just for some cool info from Ionbond:


CVD
CVA
PVD
PACVD
Tetrabond™
Laser Hardening
Glossary
FAQ
Articles
PVD Technology

Physical Vapor Deposition (PVD) is a method for producing metal-based hard coatings by means of generation of partially ionized metal vapor, its reaction with certain gases and by forming a thin film with a specified composition on the substrate. Most commonly used methods are sputtering and cathodic arc. In sputtering, the vapor is formed by a metal target being bombarded with energetic gas ions. Cathodic arc method uses repetitive vacuum arc discharges to strike the metal target and to evaporate the material. All PVD processes are carried out under high vacuum conditions.

The Ionbond PVD process is used for the deposition of coatings made of nitrides, carbides and carbonitrides of Ti, Cr, Zr and alloys like AlCr, AlTi, TiSi on a large range of tools and components. Applications include cutting and forming tools, mechanical components, medical devices and products that benefit from the hard and decorative features of the coatings.

The typical process temperature for PVD coatings is between 250 and 450 °C. In some cases, Ionbond PVD coatings can be deposited at temperatures below 70 °C or up to 600 °C, depending on substrate materials and expected behavior in the application.

The coatings can be deposited as mono-, multi- and graded layers. The latest generation films are nano-structured and superlattice variations of multi-layered coatings, which provide enhanced properties. The coating structure can be tuned to producing the desired properties in terms of hardness, adhesion, friction etc. The final coating choice is determined by the demands of the application.

The coating thickness ranges from 2 to 5 µm, but can be as thin as a few hundred nanometers or as thick as 15 or more µm.

Substrate materials include steels, non-ferrous metals, tungsten carbides as well as pre-plated plastics. The suitability of the substrate material for PVD coating is limited only by its stability at the deposition temperature and electrical conductivity.

http://www.ionbond.com/en/technology/pvd/




CVD
CVA
PVD
PACVD
Tetrabond™
Laser Hardening
Glossary
FAQ
Articles
CVD Technology

Chemical Vapor Deposition (CVD) is a method for producing low stress coatings by means of thermally-induced chemical reactions. The material of the coating is supplied to the coating zone as vapor of the respective precursor. The vapor then either decomposes or reacts with additional precursors, thus producing a film on the substrate. The precursors are continuously fed into the reaction zone and by-products are removed. CVD processes can be carried out under vacuum or at atmospheric pressure.

The Bernex™ CVD process has been developed in the early 1970s. The deposition process uses metal halides as coating precursors, such as TiCl4 or AlCl3. Over the years, the technology has been continuously improved in order to respond to increasing market requirements to quality of the coatings, reliability and productivity of the process and equipment.

The CVD process is used to deposit 5 to 12, in special cases up to 20, µm thick coatings. Materials employed are TiC, TiCN, TiN and α or κ aluminum oxide (Al203). They are applied as single or multi-layers on inserts for cutting applications, forming and molding tools like punches, extrusion and trimming dies and various mechanical components subject to abrasive or corrosive environments.

The typical process temperatures for Bernex™ CVD coatings are between 900 and 1050 °C for the HT CVD and between 720 and 900 °C for the Bernex™ MT CVD process.

Substrate materials are tungsten carbides, tool steels, high temperature nickel alloys, ceramics and graphite. Tempered steel tools and components require heat treatment after coating to re-establish the required hardness.

Low stress
Exceptional adhesion of the coating due to formation of the diffusion bond
High load bearing capacity
Excellent coating uniformity, independent of part geometry
Possibility to coat complex geometries, including certain inner diameters

And here is the list of coatings on Sputtek's site:
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And some good links here straight from Spyderco's Michael Janich:

http://spyderco.com/forumII/viewtopic.php?t=66410
 
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Sorry, should've clarified. I'm basing most of what I know on the information provided by Ionbond who does the DLC for Zero Tolerance and Spyderco, IIRC. And also IIRC, both Spyderco and ZT use TiCN as their DLC coatings via CVD for most of their blades, but I could be wrong.

As I understand it if a manufacturer says they're using DLC, then they should be using DLC not using TiCN... DLC and TiCN are very different coatings, and using one in place of the other would be very strange. DLC is the name of a specific coating, it has a few subtle variations that can be applied, but TiCN would not fall within that range.

The coating I'm using on my blades is definitely DLC. DLC is not listed on Sputtek's website for some reason, but they do apply it and as I understand it is one of their most popular coatings.
 
As I understand it if a manufacturer says they're using DLC, then they should be using DLC not using TiCN... DLC and TiCN are very different coatings, and using one in place of the other would be very strange. DLC is the name of a specific coating, it has a few subtle variations that can be applied, but TiCN would not fall within that range.

The coating I'm using on my blades is definitely DLC. DLC is not listed on Sputtek's website for some reason, but they do apply it and as I understand it is one of their most popular coatings.

Yeah, I was remembering a little inaccurately. I went back and reread a thread where Spyderco said they did TiCN on their foreign knives and DLC on their US made knives.
 
There are several types of DLC coatings, produced with different technologies, such as PVD (sputtering) and PACVD

2jcd42.jpg
 
There are several types of DLC coatings, produced with different technologies, such as PVD (sputtering) and PACVD

Interesting! I actually didn't know that anyone applied anything they called DLC via the CVD process!

The coating I tested was DLC applied via PVD (which would be 'sputtered DLC' in your chart).... Even only talking about PVD applied DLC there can be variations because the coating parameters (like thickness for instance) can be altered, and the carbon sputtering target used as the source of the coatings can also be slightly altered in chemistry to achieve different results.

CVD coatings are largely unsuitable for high end knife blades (as I understand it) as they normally have to be applied at high temperatures, which would affect the heat treatment of the blades.

Plasma Assisted CVD (PACVD) is pretty different again in terms of process, I don't think I've talked to any companies that offer PACVD.
 
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