Paul Bos, heat-treating and The Outsider

Jim March

Knifemaker / Craftsman / Service Provider
Joined
Oct 7, 1998
Messages
3,022
It was a long strange trip, but The Outsider is done. For those of you joining
in late, it's a custom knife of my own semi-radical design. It's in flight to
North Carolina now where it'll be sheathed by Scott Evans of Edgeworks
Manufacturing; Scott has a great reputation and was easy to work with during
the process of designing the sheath and being willing to do something based on
my ideas; that's also true in spades of Harald Moeller of Canada, the maker.

At one point, Paul Bos was going to be involved in the heat-treat.

Note the past tense.

There were several reasons I picked Paul for the heat-treat. In a phone
conversation, he talked about the numerous makers who'd continued to use him
over the years, and all sources said his heat control abilities were very
precise, very repeatable. The biggest negative voice was Ernest Mayer, who'd
come up with a lower-temp tempering cycle that per some sources increased the
toughness but reduced ultra-high-temp operating ability - as in, jet engine
temps such as the turbine blades ATS34 was originally designed for. Paul spoke
with pride on never changing his "recipe" since his jet engine days, which
bothered me a bit but...lots of people have used him.

The first problem was that Harald's steel supplier gave him 440C billed as
ATS34. It's a fairly common point of confusion in the industry; even during
grinding it's apparantly *really* hard to tell them apart. Paul heat-treated
it at his usual (degrees F) 1950/cool/950/cool/950/cool recipe and it came out
Rockwell 55. Ooops...too low, he checked, sure enough it's 440C.

Damn. Harald EMailed me, asked me to call him collect and broke the bad news.
He explained that we could start over in real ATS34, we could go with the
slightly-lower-hardness 440C which would still be a decent blade, edgeholding
would be a bit low but then again it ain't a utility piece...or Paul could
re-anneal and do it up in a 440C recipe. I EMailed a small group of people
with more metallurgical skills asking for advice and Alan Folts got back to me
saying that #1, this is kinda common and #2, re-annealing wouldn't work. The
440C would come out like crap, basically.

That's when I phoned Paul up the next morning; Paul had already decided on the
re-anneal, he explained that this happens all the time, he'd had batches of up
to 100 custom knives at a time turn out to be 440C versus ATS34 and that he
could re-anneal, do it up 440C style and it'd be good 440C. I was disappointed
he hadn't left Harald and I with the option of lower-Rockwell higher toughness
because after Alan's EMail, I was ready to go that route. This was all 1 month
or so before Knifignugen and I *really* wanted it for Arizona.

Harald then said that when the re-annealed and treated 440C came back, he'd
examine it and if it was OK, we'd complete it.

It wasn't. Harald noted a "mottled, bubbly" finish indicative of trouble, a
bit of whacking and the tip popped off. He then broke it in half to examine
the grain structure and send the scrap back to Paul.

I then told Harald not to rush, to do up the ATS34 right and forget K'Nugen
timetables. Harald did additional research followed by his own heat-treat
using the Ernie Mayeroid recipe of 1925/375/375 preceded by a home-brew
cryo-treat of burying it in dry ice for 16 hours in an old freezer. His newest
tests show this is a *great* recipe just like Ernie says it is, and it's now
unlikely that Paul Bos will ever touch another Moeller ATS34 blade again.

KUDOS TO HARALD MOELLER for the honesty to admit what happened and be willing
to eat the labor of the first now-broken blade because it didn't meet his
quality standards. $hit happens, but integrity needs to be a constant.

At K'Nugen, I related this tale to Kevin the Mad Dog, who explained that
re-annealing was the mistake. Per him, to just do the heat cycles over again
in 440C fashion would have been better. Alan Folts had predicted the problem
beforehand, although his attitude in such cases is to just scrap the 440C part
entirely for top performance. Which of these gents is correct is beyond my
ability to say, but I'd trust either before Paul.

Paul is not an innovator. His line of "I've been doing it this way for 20+
years" falls flat in my ears; it's obvious to me that a knife or sword doesn't
have to operate at temps that would kill a human. Metallurgy is tradeoffs, and
if I can trade high operating temps for better human-range temp functionality,
hell yes Ernie, that's a great idea. He's also not a troubleshooter, and he
was arrogant in denying me the option of "softer tougher 440C".

All that said, so long as no special problem arises his temp controls *are*
consistent, he practically never does a genuine bad heat-treat due purely to
his own screwups. If you're trying to do a solid basic knife without pushing
the performance envelope to the max, he's good, fast and fair and has without
question helped a lot of smaller knifemakers over the years either directly or
via the heat-treats he did for the late Bob Engnath.

I respect Paul, but I wish he'd test, experiment and innovate more. He's had
no competition for a LONG time, and that's part of the problem. The sooner
Ernest Mayer of Black Cloud knives has his heat-treat sideline up, the better
so far as I'm concerned. The custom knife biz is booming, it can support two
major specialty heat-treaters with ease.

Jim March

 
Just an aside to this sad fiasco.... I don't know if this holds true for all 440-C and all ATS-34, but all of my ATS-34 has a darker skin than the 440-C. This is bar stock, not precision ground,that I am talking about. I also heat treat all of my own blades in an old electric heat treat oven that I have retrofitted with an OMRON controller and new "r" thermocouple. I have been doing the 1950/-70F(dry ice/acetone)/975/cool/975/cool

What is the practical advantage of the lower temperature tempering?
 
Please allow me to flesh out Jim's story a bit...

I got the following information from rec.knives. To bring it up to date I have been told that Pat Crawford and others have also went to this recipe with good results....

Rick Schultz mission@beach.net

ATS-34 is among 3 steel choices we are considering for a new production
knife we are working on. Having had meetings with Hitachi, we obtained
the following technical data on heat treat properties. We were
particularily interested in which curve offered the best corrosion
resistance. ATS-34 has a double hump hardening cycle and the lower
temperatures offered the better corrosion resistance. They offered the
following data.

Hardness (RC) Tempering Temperature (Quenched at 1,070
C)
62 As Quenched
62.8 100 C
60 200 C
56.8 300 C
57.2 400 C
58.8 500 C
60.8 550 C
54.8 600 C

Their summary, ATS-34 tempered at 230 C has higher impact toughness and
corrosion resistance than ATS-34 tempered at 510 C.

From a report by Yoshi Tazunoki, Engineer, Hitachi Metals, Long Beach,
CA.

Hope this helps
Rick Schultz
Mission Knives & Tools, Inc.
http://www.beach.net/MissionKnives/


Thank you for the info. I have been unsuccessful in getting this info
from Hitachi. This backs up what I have been saying for some time- that
the makers, companies and treaters that are working with ATS-34 are
tempering at the higher temperature, and not getting the best qualities
that ATS can give.

From: Ernest Mayer ernest@blackcloud.com

ATS-34 is a true stain resistant steel. The nominal composition (I have
seen some certified comps for billets, and they vary almost not at all
from nominal), is

1.05 C
.40 Mn
.03 P
.02 S
14.0 Cr
.35 Si
4.0 Mo
I have commented before in this group about performing the correct heat
treatment for ATS-34, I will repeat it. The temper must be done at 375F
or so. The temper done in the 900F range produces grain growth which is
directly responsible for loss of toughness and loss of corrosion
resistance. I snail mailed Ben Ogletree a copy of the ASM section on
heat treatment of stain resistant steels, it says the same thing.


shevelin@aol.com

I have not heat treated ATS-34, but have some experience with 134-CM,
which is the American brother of this steel, also CPV-10M. All these
steels are recommended as having their highest hardness and abrasion
resistance at about 1,000 degrees F. tempering. This after a hardening
at 1950 to 2150 deg F. The tempered blades are about 61-62 Rockwell C
when double tempered at 1,000 deg. A cryogenic quench doesn't hurt
matters much either....

I have never had a corrosion problem with 134-CM after this procedure.
Blades made using the above tempering have served in the field
(military) in Panama for several years without rusting -- the handles
looked bad though due to high humidity and rough use.

Please advise me the proper technique for handling these steels and
perhaps I can comment further.

Scott


Scott,
The proper tempering temperature is 375F to about 450F, depending on
final hardness desired. There IS a real difference in impact toughness
between a high temp temper and a low temp temper knife, which translates
to real world increase in corrosion resistance and toughness. I qoute
from my ASM Heat Treating Handbook, "Although the strength, elongation
and hardness curves shown in fig. 4 and 5 appear to have the same
general form as those of low-alloy steel, the increase in tensile
strength and hardness between750F and 950F may be associated with a
serious decrease in notch toughness, while tempering on the high side of
the temperature range generally coincides with a decrease in corrosion
resistance. The tempering temperatures most frequently employed to
achieve desired hardness and other mechanical properties are included in
table 4. The Izod impact curves in figure 4 and 5 reveal a loss of
impact strength when parts are tempered within the range 700F to 1200F.
Tempering within this range also results in decreased corrosion
resistance, particularly resistance to stress-corrosion cracking (fig.
6). Double tempering (cooling parts to room temperature after the first
tempering treatment) also is beneficial for resistance to stress
corrosion."

Note that the loss in toughness is describes as "serious". Do not let
anybody tell you that tempering on the high side makes little difference
in the toughness of the knife. You can run your own tests as I have to
convince yourself. When you are purchasing an ATS-34 knife, ASK for the
complete heat treatment procedure employed by that maker, and avoid the
high temperature temper. It will fail at the wrong time. You may not
notice it in regular service, but the limits of the knife will be
compromised. Hitachi also recommends the lower temper temperature for
their steel.

From: Ernest Mayer ernest@blackcloud.com

It is most likely as you say, there is something wrong with the heat
treatment of the blade steel. I have been posting on this group before
about many makers using the wrong tempering temperature for stainless
steels. 440C and ATS-34 do not temper at the higher temperature like A2,
O1, etc. They temper at 375F, not at 900F as most are doing. 700 to 1000
is the bad area for stainless steels, as this is where grain growth can
occur. This is a direct cause of loss of toughness and loss of
corrosion resistance as evidenced by unscientific, side by side
comparisons with properly and improperly treated steel. This may be the
cause of the failures. This info is not my opinion, it is documented in
the metallurgy literature, and is the results of some of the research I
was involved with in 1983-1986.
 
I use the lower temp temper also // Smart
smile.gif

 
You have convinced me. I have been following the Bob Engnath directions which mirror Paul Bos. Tomorrows blades get double tempered at the lower temperature of 375F after the dry ice acetone freeze. I'll tell you if I can detect the difference! One thing for sure. It will take less time to get to 375F in my little old oven than it takes to get to 975F

Thanks
 
Rouppe, Harald was buying flat stock, ground. This requires less grinding which is good; with ATS34 you basically get "one shot" at heat-treating and if you "blow one shot" heating it up during the grinding, that was it. Too bad.

But it made it harder to ID the steel.

My understanding is that the colder cycle increases toughness at the same Rockwell. Small cracks have a harder time forming...I'm no metallurgist, so I hope others answer in more detail.

Jim March
 
JIM
There is one question? Was the 440c ats 34 sheet stock or rolled bar? Which way was the grain cut if it was sheet?.. NEED I SAY MORE

The other thing is when people get it in there heads to do the same things OVER AND OVER it is a tragedy... There are processes
being developed dailey that change our industry . Remember asking me about 12c27.
Same rap as your getting. The heat treat was not proper so the steel preformed like crap..
Some of the new processes - the ROI is a mute point some make a real difference.. I recommend (if you dont do your own )heat treat with Howard Clark for carbons .. As for stainless I use the same basic process of the lower end temper. And of coarse I do my own thing having a microscope. It gives me the insight and truths ... that are not heresay and Witchs brews... hahahah.
Im glad to see that E. MAYER has taken this stainless steel heat treating problem by the BALLS :}. SALUTE MR MAYER..


 
Harald is working from sheet stock, he's a stock removal guy like Ernie Mayer, Kevin McClung, Chris Reeve and Jerry Busse.

I have a Moeller thrower so I know for certain he knows how to get the grain aligned right. The guy is *good*, that thrower (Viper2, $50 used at a knife show) is an excellent example of a hand-ground knife and made me quite pleased with my choice to use him.

Jim March
 
Well, I use the lower end of the tempering cycle also, and do the dry ice/acetone thingy and have yet to have an ATS-34 blade come back busted, and like Darrell says, having a microscope handy enables you to fine tune the heat treat even more. Nuf Said
 
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