I don't have any idea how deep/wide slot canyons are, but here is the description of the gorge used to do a limited view of the sky test in the Equipped to Survive Foundation's "Second Evaluation of 406 MHz Location Protocol Distress Beacons".
"Inland Scenario Foxtrot was developed to assess the ability of the COSPAS-SARSAT system to receive an alert and derive a Doppler location in circumstances where the beacons had a very narrow and limited sky view, as when survivors are located in a narrow canyon. The location selected was within a narrow rock gorge through which flowed Aptos Creek. Estimated depth of the gorge where the beacons were placed was approximately 30-40 feet plus trees lining both sides. It was approximately 15-20 feet wide at the bottom and approximately 30-40 feet wide at the top at the point the PLBs were located. The beacons were placed on a rock shelf located to one side of the gorge.
The only access to the selected location was by traveling up the creek approximately 100 yards, which ran from wall to wall of the gorge in places. Ritter donned insulated waders and one of the Coast Guard Rescue Swimmers donned his dry suit and they waded up the creek, which was approximately 3 feet deep at its deepest, to place the beacons on the rock bar. The beacons were turned on sequentially with a 15-second interval and were left on for approximately 4 hours which allowed for 3 LEO satellite passes.
All three PLBs were picked up by the GOES 10 satellite, which would provide an "immediate" alert in an actual emergency. The ACR Prototype PLB was also picked up by GOES 12. It has been suggested by various experts that this may be the result of a lucky reflection off the rock wall of the gorge. ACR suggests, "the result is more a case of the beacon having a strong transmitter than it is a 'lucky shot'. Without ample power a reflected signal could never make it to the GOES 12 satellite."
All three PLBs were picked up by the Low Earth orbiting (LEO) satellites on their first pass, about 25 minutes into the test, which provided a Doppler location."
One of the PLBs did get a GPS fix in the gorge - likey from a reflected signal.
The full test results are at
http://www.equipped.org/406_beacon_test2_toc.htm