It is OK to use, but if you are installing the heavier grade wool, it really isn't necessary. Just build up the satanite in two or three layers. I just looked, and don't even see it on the HTT&R site. Rigidizer's main use is on uncoated wool linings like pottery kilns. It makes the fibers less friable.
What you assumed was ruined by freezing may be restorable by heating in a double boiler ans stirring well. You may need to add a little water, or even simer it a bit to get it right. Rigidizer is available at masonry and refractory suppliers ( boiler and furnace supply), as well as pottery supply shops.
I think Rigidizer is close to waterglass (sodium silicate). You can probably use that in its place. It costs about $24 a gallon with free shipping on eBay.
DIY rigidizer is often just hot sugar syrup. You want it medium thick. It will smell and smoke a bit when firing the forge, but that will go away.