Spyderco sharpens their knives by hand, so they vary by a few degrees, but they are all pretty close to 15 deg. per side.
Well, I would say, the jury is still out on this one. Phil Wilson, who certainly knows a bit about bladesteels, still thinks that S30V is the steel that offers the best trade-of for any non-chopping type blade. I would say that it is still considered one of the premium bladesteels. CPM-154 is still very rarely used. 154CM has a loyal following, but it is not as wear resistant as S30V and not as fine grained either. VG-10 is a favorite for many but it is not as wear resistant and according to the numbers not tougher either, and D2 is only marginally stainless, not very fine grained, nor very tough, but very wear resistant.
In the end it boils down to you presonal preference. Which brings me to your question about ranking steels. There is no such thing as a "steel ranking". All you can do is to compare certain characteristics, such as hardness, toughness, wear resistance, ductility, corrosion resistance, just to name the most obvious and then make a decision where you want to put you trade-of, since it is impossible to optimize all characteristics at the same time (although, compared to a poor steel, it is possible for a good blade steel to excel in serveral categories at once). The other "ranking" is simply the combined experience of the people frequenting this forum.
However, there is one thing that most people on this forum would agree with: That the Native II is currently probably THE best deal in the knife market today.