Some further work with a model on edge retention comparing ZDP-189 and SPGS

Cliff Stamp

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Recently I noted a simple model to apply to edge retention and how to use and interpet it to comment on the relative performance of steels using a large comparision of several S30V and ZDP-189 blades :

http://www.bladeforums.com/forums/showthread.php?t=416896

Recently I set out to benchmark a U2 in SGPS at 62 HRC and chose the closest knife in geometry a Jess Horn in ZDP-189 at 65 HRC. Both knives have high hollow grinds on 0.095" thick steel. The U2 was reground by Krein and the edge is sharpened flat to the stone at 3.9 degrees per side. The Jess Horn is also sharpened in the same manner but since the grind is sabre/hollow it is significantly more obtuse at 7.9 degrees per side.

The first trial run was using a new cord which is very thin, only about a mm or so wide. A 50 g section of mild steel bar provided the tension. 20 m of 1/8" ridged cardboard was cut through 20 cm sections. The cutting was done on a slice through 3 cm of edge with the sharpness measured on the middle two cm. The 20 m was cut in 12 intervals with each each point consisting of an average of four sharpness measurements and five runs were made with the U2 and four with the Jess Horn. The results :

card_1_8_zdp_spgs_45.png


This is the kind of rough trial result that never actually leaves the lab. There are a couple of interesting trends but the graph is too noisy to tell if they are real or just random. The cord wasn't that consistent, repeat cuts at the same point could generate 0.75 cm and then 1.25 cm. There was far too much tension being used. The cord basically busted under the weight and tended to get tore apart rather than cleanly cut. So drop the weight back to 30 grams and take eight measurements of sharpness at each point. I ran 5 trials with the U2 and 6 with the Horn. I split the run up into 15 intervals to give more data to allow a better curve fit. Now at each point there was 40-48 measurements of sharpness for a total of 600-720 points in total. This gives :

card_1_8_zdp_spgs_30.png


The U2 gives better edge retention. To determine how much do a simple transform, take the ratios of the two data sets after subtracting the initial sharpness. Fit this curve to the same power law model. The coefficients of this curve then show directly how much the edge retention of one knife is ahead of the other. The transform :

Code:
sr(x)=rr1*x**(rr2)
fit sr(x) 'card' every ::1::15 using:(($4-27.5)/($2-27.5)):(($5/$4)**2+($3/$2)**2)**0.5*($4/$2) via 'params\rr.prm'

The results :

card_1_8_zdp_spgs_ratio.png


The power law fit shows the power is barely different from zero which you would expect as these two steels should blunt in the same manner. The multiplier coefficient showing that the Jess Horn is blunting at about 75 (8) % as fast as the U2. Now this raises some interesting questions because the Jess Horn compared well to number of S30V blades and looking at SGPS it is essentially S30V with a lot less vanadium and a little more moly. Thus you would expect a greater hardening responce (vanadium ties up a lot of carbon) and a greater secondary hardening but the wear resistance should still likely favor S30V. I would be really curious if SGPS was tempered high.

Now is the difference seen here due to the hardness of the S30V vs SGPS? Or is it the difference in primary edge angle. If so how does the reduced edge angle have this effect because all the blunting is constrained to the 15 degree microbevels (checked under magnification) and the initial sharpness is near identical for both so it doesn't seem to effect the measure of sharpness. It could be because the lower edge angle decreases the lateral forces around the edge which I can see because there would be a significant reduction in localized distortion.

The above proposes the following work would be of interest. Take a few blades and run them through the above work with standard micro-bevels and 5,10,15,20 degree primary bevels, or as fine as increments as desired and see if there is a definate correlation. One other thing which comes to mind is that the tension used could effect the results. Consider a 4.5 tpi vs 11 tpi saw ran both very light and very hard cutting woods and the performance ratio is massively different. This would then logically imply that slicing with a very coarse micro-tooth pattern would favor a high cutting load and low cutting loads would favor finer finishes.

One thing I would note is that I really don't expect this kind of numerical detail from a general hobbiest looking at edge retention. However from makers/manufacturers who are seriously trying to produce meaningful data and make definate statemens about steel performance, the above is an illustration of how to do it using standard statistical methods. Anyone who wants to do the analysis but isn't sure of the math drop me an email and I'll either do it for you or give you the necessary code to do it yourself. There are freeware programs on any platform which can do this very quickly.

-Cliff
 
Cliff,
Concerning the Rockwell hardness of the U2 and Horn steels:
- SGPS in U2 is HRC 62; the value 64 was mistakenly printed on boxes (explained by Peter);
- I asked info about the HRC value for Delica at Spyderco forum and, unfortunately, was ignored (strange, because Sal promptly answered my question about the hardness of BG-42 in a new CF Military - is HRC 61). I wouldn't be surprised if Spyderco runs ZDP-189 in Delica (and Horn) lower then originally pretended (65). Maybe you could try to ask an info (with better luck).
I think it is important for your interpretation to be sure about the hardness.

Franco
 
Cliff, in addition, the content of ZDP-189 is not known. It seems, it is not just 'straight' C 3%, Cr 20%. Hitachi, simply, did not release the complete data.
Sal's comment on the Rockwell hardness is very old. I wonder if he decided later to lower the hardness?
There is in meantime an interesting discussion on this subject, Spyderco site:
http://spyderco.com/forums/showthread.php?t=23641

Franco
 
ZDP-189 also contains molybdenum and tungsten, the amounts aren't known, though I would guess it's approximately 1% molybdenum and .2% tungsten.
 
Hi Franco,

sal isn't always available to read or anwer questions on the forum, sorry.

I do travel quite a bit and I do have a "day job".

The Rc on the Horn is called out for Rc65, same as the Calypso ZDP.

Hitachi is not generous with their info on ZDP. Even their heat treat specs seem to have some "tricks" that they don't tell "unauthorized heat treat centers". Our ZDP blades are made and heat treated (by Hitachi heat treaters) in Japan. We've had good success and no complaints from the performance of our ZDP models.

In fact performance has been so well accepted that we're adding ZDP Endura4and Delica4 models to the regular lineup in '07. (British Racing Green)

We've not used SuperGold yet. It is quite a bit more expensive than ZDP to purchase and process, and we've already got quite a few projects in the works.

Maybe we'll do a short run of SuperGold in the Caly3 pattern once the model is out. After the ZDP run.

Cliff, fun information. thanx for the effort.

sal
 
Sal, I am sorry if my post sounded unpolite. In fact, I hoped that Kristi would give me an answer.
The Rc on the Horn is called out for Rc65, same as the Calypso ZDP.
I hope the same is true for ZDP Delica (HRC 65). Actually, I asked about the hardness of ZDP Delica.

Franco
 
No problem Franco, I was just givin' you sh*t for fun.

We try to take advantage of the high hardness capability. I think most would agree that if 65 is supposed to be the "optimal" hardness, we would lose by not using it. We try to get as close to the "optimal" hardness as is possible for any steel.

sal
 
Franco G said:
Cliff, in addition, the content of ZDP-189 is not known. It seems, it is not just 'straight' C 3%, Cr 20%. Hitachi, simply, did not release the complete data.

Yes, I have heard this before, however I wonder how much of this is fact and how much is simply a way to create mystique about the steel. I'll make a note of this on the materials page that there is some debate about the existance of additional materials elements. It certaintly seems an interesting way to approach a high wear stainless as you would assume if it wasn't a P/M the carbon would bind up a tremendous amount of the chromium and you would end up with something like a high wear version of D2. This is why I wonder before if the P/M process doesn't shift the K1/K2 carbide formation rates.

-Cliff
 
Cliff Stamp said:
Yes, I have heard this before, however I wonder how much of this is fact and how much is simply a way to create mystique about the steel. I'll make a note of this on the materials page that there is some debate about the existance of additional materials elements. It certaintly seems an interesting way to approach a high wear stainless as you would assume if it wasn't a P/M the carbon would bind up a tremendous amount of the chromium and you would end up with something like a high wear version of D2. This is why I wonder before if the P/M process doesn't shift the K1/K2 carbide formation rates.

-Cliff
I just told you it has molybdenum and tungsten in it. It lists the two elements on a general Hitachi knife steel data sheet, it does not list the amounts. I would guess it is similar to Cowry-X, having 1% Molybdenum, and .2% tungsten instead of .2% vanadium.
 
Larrin :

Larrin said:
ZDP-189 also contains molybdenum and tungsten, the amounts aren't known, though I would guess it's approximately 1% molybdenum and .2% tungsten.

Larrin, do you really want people to blindly accept statements you make without any evidence in a cult like manner? If not then you need references. What is the basis for the guess on composition? Is it simply because Cowry-X has those elements or have the two steels been compared directly and ZDP-189 has a similar hardening responce to Cowry-X, or corrosion resistance, grindability, etc. ?

Looking at the secondary hardening responce, ZDP-189 peaks at around 540C which is where molybdenum induces secondary hardening. Chromium secondary hardening is lower because it doesn't require as high a temperature to diffuse. I suspected ZDP-189 had molybdenum when I first saw that in the data sheet. Plus some molybdenum would tie up some carbon and enhance the corrosion resistance by allowing more free chromium. Without other carbide elements it looks like the carbon would tie up a massive amount of the chromium, unless as I noted the P/M process switches the type of carbide which is formed. It would also make sense for it to have a small amount of a grain refiner like Vanadium to pin the grains so they didn't sustain growth during soaking.

However until I saw actual data from Hitachi I would not in general strongly propogate such inferences as fact. I would like to see the information from Hitachi which say definately it contains other alloying elements. I'll then update the reference files for the above work.

-Cliff
 
Cliff Stamp said:
Larrin :



Larrin, do you really want people to blindly accept statements you make without any evidence in a cult like manner? If not then you need references. What is the basis for the guess on composition? Is it simply because Cowry-X has those elements or have the two steels been compared directly and ZDP-189 has a similar hardening responce to Cowry-X, or corrosion resistance, grindability, etc. ?

Looking at the secondary hardening responce, ZDP-189 peaks at around 540C which is where molybdenum induces secondary hardening. Chromium secondary hardening is lower because it doesn't require as high a temperature to diffuse. I suspected ZDP-189 had molybdenum when I first saw that in the data sheet. Plus some molybdenum would tie up some carbon and enhance the corrosion resistance by allowing more free chromium. Without other carbide elements it looks like the carbon would tie up a massive amount of the chromium, unless as I noted the P/M process switches the type of carbide which is formed. It would also make sense for it to have a small amount of a grain refiner like Vanadium to pin the grains so they didn't sustain growth during soaking.

However until I saw actual data from Hitachi I would not in general strongly propogate such inferences as fact. I would like to see the information from Hitachi which say definately it contains other alloying elements. I'll then update the reference files for the above work.

-Cliff
Please go read my posts again. I gave a reference for it containing molybdenum and tungsten. I said that my percentages were guesses based on Cowry-X. The Japanese always copy each other, even hire competing companies to make their own products.

Why do you feel the need to attack me? I'm simply sharing information, and adding my guess to go along with it.

Edit: Here is my reference:http://playground.sun.com/~vasya/YSS.gif Originally posted by nozh2002.
 
That's excellent, no more rumors and assumptions. I updated the information accordingly.

-Cliff
 
Claiming people’s statements are assumptions and rumors without anything to back up the claim is itself spreading rumors and misinforming. Well done Cliff you’re doing what you accuse others of. Larrin don’t get discouraged everyone is attacked by Cliff at one time or another. That is why there are very few long-term supporters of Cliff even though he has done some very interesting tests. In the past he ran all over the internet acuseing a lot of people of hype, hype this and hype that. Sometimes he was right and many times he was not. Now he is doing the same old thing but acuseing people of spreading rumors, assumptions and misinforming.
 
db said:
Claiming people’s statements are assumptions and rumors without anything to back up the claim is itself spreading rumors and misinforming. Well done Cliff you’re doing what you accuse others of. Larrin don’t get discouraged everyone is attacked by Cliff at one time or another.
I'm not going to worry about it. :)
That is why there are very few long-term supporters of Cliff even though he has done some very interesting tests. In the past he ran all over the internet acuseing a lot of people of hype, hype this and hype that. Sometimes he was right and many times he was not. Now he is doing the same old thing but acuseing people of spreading rumors, assumptions and misinforming.
You can rest assured that I won't be spreading any rumors, at least not on purpose.
 
Larrin said:
You can rest assured that I won't be spreading any rumors, at least not on purpose.

Rumors are statements without sources like "A lot of makers believe ..." there is no way to validate that statement as it is undefined, they are the lowest form of communication. People won't name the makers simply because it prevents refutation - and of course it is always better to be vague than to say the makers are Bill and Joe who live down the street and sell knives at the local flea market.

If you say something like "I believe ..." it isn't a rumor because the source is identified. It can become a rumor when the source is lost which happens once you become vague and no longer say "I believe ..." but just state the rest of it. Often this is done intentionally because any definate statement of the source would weaken the rumor "Bill the guy net door who talks to his singing cod fish said ..." isn't as strong as "I heard ...". Plus when you leave out the personal qualification it implies generality. "I have found ATS-34 to have problems with corrosion resistance." isn't nearly as strong as "ATS-34 has problems with corrosion resistance." The latter is how rumors get started.

Just consider, if someone made a very critical statement about Devin's knives would you want people to accept what they said on faith or would you want them to be skeptical and demand demonstrative proof and specify the exact problem and how it was determined/evaluated. This works both ways, you have to expect people to apply the exact same demands to any statements you make.

That is what separates the shills/gossips from the people who seek truth. People who are looking for truth encourage skeptics, shills want people to accept things on faith and gossips, well they just want to gossip.

-Cliff
 
Cliff Stamp said:
Rumors are statements without sources like "A lot of makers believe ..." there is no way to validate that statement as it is undefined, they are the lowest form of communication. People won't name the makers simply because it prevents refutation - and of course it is always better to be vague than to say the makers are Bill and Joe who live down the street and sell knives at the local flea market.

If you say something like "I believe ..." it isn't a rumor because the source is identified. It can become a rumor when the source is lost which happens once you become vague and no longer say "I believe ..." but just state the rest of it. Often this is done intentionally because any definate statement of the source would weaken the rumor "Bill the guy net door who talks to his singing cod fish said ..." isn't as strong as "I heard ...". Plus when you leave out the personal qualification it implies generality. "I have found ATS-34 to have problems with corrosion resistance." isn't nearly as strong as "ATS-34 has problems with corrosion resistance." The latter is how rumors get started.

Just consider, if someone made a very critical statement about Devin's knives would you want people to accept what they said on faith or would you want them to be skeptical and demand demonstrative proof and specify the exact problem and how it was determined/evaluated. This works both ways, you have to expect people to apply the exact same demands to any statements you make.

That is what separates the shills/gossips from the people who seek truth. People who are looking for truth encourage skeptics, shills want people to accept things on faith and gossips, well they just want to gossip.

-Cliff
Thank you, Cliff.
 
In case it wasn't clear, I have never found you to be the type who engages in such activities. I basically rewrote everything I had on stainless steels due to the FAQ you wrote for Thomas which forced me to rethink how I was separating steels after talking to Devin and reading Verhoeven's work in detail. That was annoying because I had just got the page to a decent working state and then had to rewrite the entire thing. The fairly absurd bit was that Alvin had been saying the same thing on rec.knives for years (advocating very fine carbides/high hardness) but for some reason I was thinking about stainless steels very differently than tool steels. Probably simply because everyone else did, AEB-L=440A, etc. .

-Cliff
 
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