First of all, you can do lots of things to make a single room warmer, make sure that the room is getting the heat it is supposed to be getting by making sure the flow of heat, being forced air, hot water, or what ever, it going to that room, sometimes just making simple damper adjustments can make a huge difference. Reducing the amount of heat going up is the big thing, Make sure his attic is still insulated, we had a home that never kept the MBR warm, turned out the cable guy had pushed all the insulation way over to find the wall for dropping down his cable lines. We just pushed the insulation back, and the room warmed right up. Drafts are another big deal and often easy to fix, one poorly sealed electrical outlet on a cold wall can cost up to a buck a day or more in lost heat.
If the heat is not getting to the room and you have a boiler, consider adding a zone valve or a second thermostat and controller which allows you to literally pump more heat into just that room.
Other things to remember are either keeping doors open or shut, if his room is colder with the door shut, let him fall asleep with the door shut then open it for more heat circulation later.
Hold old the child is also matters, I would not add any supplementary heater to any childs room who is not old enough to understand about fire risks, a tee shirt thrown carelessly across a heater may start a fire.
My mother in law had great results with adding a heated mattress pad, that way the heat came up to her, not her waiting for heat to radiate down. She had it on a timer, it would come on about a half hour before her bed time and go off about an hour later, her bed would be warm, she was comfy, and by the time it went off, she was asleep and her body heat was enough to keep the covers and her warm.
If you can manage it, there are usually low cost "energy Audits" that are performed by your local utility. often they even supply a lot of the materials that fix the problems for free or reduced cost. Ours gives a few month discount on your power and heat bill if you take it and follow up on the recommendations. I got 30 compact flourescents, a case of caulking, some new ideas on damper settings and a water heater insulation blanket and some other things for free.