Talk to me about “dryo” treatment

Ken, I agree that it is not a great significance since the exact temperature of DI is not needed. -70°F will be low enough for most situations.

DI is -110°F, a Blade in a DI slurry is -105°F, and loose DI chunks drop the blade to -70 to -90°F°F (depending on fineness of DI pieces). The finer the DI pieces the faster they sublimate and thus drop the surrounding air/CO2 atmosphere temperature. The difference is that the gaseous CO2 acts as an insulator between the blade and the solid DI, whereas the liquid alcohol is a conductor.

Technically, the best way to use solid DI to cool a blade would be to place the blade between two slabs of DI in a well-insulated cooler and leave it there for an hour. I am sure burying it in a cooler filled with DI chunks would cool it nearly as well. As we both agree, this is just technical semantics, and the real-world difference to the blade is small.


My DRYO method (I have never called it that, BTW. It is called a sub-zero bath.)
I use a "whole fish pan". It has a rack that is useful to lift out the blades when done.
I put in the alcohol to about half depth. I crush up the DI into small pebble size pieces and add the broken DI to the alcohol slowly. At first it will boil like crazy as the DI quickly sublimates. After a few minutes it settles down to a nice "simmer". As the temp of the alcohol drops you can add as much DI as needed to make a slurry. Since you can't store it, I usually add the rest of the DI when I am ready to start adding blades. I add the blades one at a time as I take them out of the quench plates and then cool them further in cold water. Quenching in oil/or plates and then cooling in a bucket of ice water will help keep the boiling down a bit, but you can put the blades into the slurry at room temp.

A word of caution:
It looks like a bath of alcohol when it settles down. The container may have frost on the outside (especially a metal pan), but that doesn't look scary. However, the bath is close to-100°F and will instantly freeze skin if you try to pick up a blade by hand. Rubber gloves aren't suitable protection. USE TONGS or a rack!

Fun stuff - After you are done with the blades and they are in the tempering oven, you can put things in the DI slurry remaining to have fun. Freeze a flower and smash it with a mallet. Freeze a rubber hose and break it in half. It isn't quite like LN, but if you have kids, it can be a fun way to show then the degree of cold you have created.

When the pan/cooler/etc. of slurry has sat around for a couple hours, give it a stir to release and saturated CO2 in solution. Pour it back in the can and give it a shake. Put the top on loosely and leave it sit until room temp, then close the cap tight. I label the can Dry ICE and use it over and over again.
 
I just checked my Igloo. It's actually 2 gallons, with a depth of 12" to the rim. There is no problem at all using about 1.5 gallons of DI for an 8" chef's knife. The DI takes up quite a bit of the volume (until it gasses off), and I only care about the 8" of the blade getting to temp. Anything with a ~12" blade or shorter is no problem. I don't care at all about the handle getting down to -100°F. So, if you have one laying around, you can use it. That's what I did, and that's usually what I end up doing....figuring out how to solve a problem with what I have on hand already. Use what you have, and if you don't have anything, you can start from scratch and use a long shallow pan. The denatured alcohol can be used over and over, so the $15 a gallon or whatever it is doesn't matter too much.
 
Just a note that a vertical tank will boil over more than a horrizontal one. Don't fill it too full.

I love talking about boiling at -100°F :cool:
 
Just to follow up a bit, I ended up ordering a "1/2" pan and lid from a restaurant supply. Inside dimensions are just under 6 inches deep, 6 inches wide, and nearly 20" long, so I can easily submerge even the largest chef knife I'd ever think of making. It's stainless steel, and holds 8 quarts, give or take, and even with just one gallon of a DA/DI mixture, I should have 3 inches of submersion to play with. I'm still thinking about getting an outer container like a plastic bin or something to set it in, more for safety reasons than anything.

Also, I picked up some aluminum quench plates. They're about 6-7/8" wide by 20" long and 1-1/4" thick. They're some big mama jamas. Nearly 20 lbs a piece... :D I'm thinking I won't even have to weigh them down, or even clamp them. hahhah

They were a little spendy, but they should last me for the rest of my life, and aluminum doesn't seem to be getting any cheaper these days. I may add a handle for ease of pickup. We'll see. I've got an old pedestal base for a bench grinder that I'll probably turn into a table for the bottom plate. We'll see...
 
One more follow up...

I heat treated my first batch of AEB-L yesterday with the new "dryo" set up, and everything went off without a hitch. I opted for 1 gallon of DA, and I'm glad I didn't add much more to my 2 gallon pan, because it would have certainly boiled over while adding the dry ice. I added about 1/2 cup at a time until it started settling down.




So on a somewhat cool (pun intendid) and related note... I had planned on going to my local Meijer grocery store to get the dry ice yesterday, but when I got there, the their dry ice cooler was empty. Back to the drawing board, I searched more local options and found that an ice cream shop downtown supposedly sells it. I'm thinking "awesome... dry ice and a scoop of icecream... back in business". I call... no answer.
So then I see there's a welding supply 20 minutes from my house that supposedly has it. I call, and they have "plenty".
Now I'm pretty sure that this is the same welding supply that gave me the run around years back, but they've since changed hands and are under a new name. I'm a little wary, but I head over and take my chances... ;)
Long story short, not only do they give me my bag of dry ice, but it was only about $15 for 10lbs (which was twice what I needed), and he even waived the hazmat fee. It was also already in pellet form, which was nice.

I asked if they happened to fill nitrogen dewars by any chance, and he says "absolutely!". I hesitantly asked for a quote for about 20L or so.

He punches some number on the computer, and I see a total of about $150 something pop up on the screen. (yikes)
Before I can say anything, he says "oh no.... we can do better than that! Let me try something else..."

He clacks a few more keys on the keyboard, and a new total pops up: $65 or about $3 per liter.

So needless to say, I'm probably going to be buying a dewar soon.... hahah
 
He clacks a few more keys on the keyboard, and a new total pops up: $65 or about $3 per liter
When I see prices like that for LN makes me happy I live here, I pay 80¢/liter for LN, or $8 for a 10 liter dewar, plus 80¢ tax

The closest welding supply wanted $6/liter, then I found the cheap place.
 
When I see prices like that for LN makes me happy I live here, I pay 80¢/liter for LN, or $8 for a 10 liter dewar, plus 80¢ tax

The closest welding supply wanted $6/liter, then I found the cheap place.
Dang... I'd say that price is gonna be hard to beat. That's awesome.
 
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