Here’s my take: Ti on Ti can work very well, but needs (expensive) manual adjustment when building the knife. When the Ti lock face is carbidized (80+ HRC) only the blade will wear until the knife is broken in, and lock-stick is completely gone.
I have several Ti/Ti Hinderers, and the action is perfect. It’s a beautiful thing: when new, you could see the tang surface breaking in. On the other hand, i have several Ti/Ti Spydercos, and they stick pretty badly, you can literally see the lock move to the other side over time - due to stick.
On the other hand, steel inserts stick less easily, and I assume are cheaper to assemble - meaning less manual work. My steel insert Spydercos are all great.