on etching? why, yes. I've etched with vinegar, carbonated soda (carbonic acid), copper sulfate (also plates metal), phosphoric acid, hydrochloric acid, muriatic acid, and (my fave) ferric chloride, as well as fruit acids. Try concentrated lime ade sometime. Any of these methods will result in a visible temper line, and you can accent the temper by successively fine polishing by hand.
Microcaust...
If you zoom in to the molecular level of the khuk blade, you've got Iron molecules, Carbon molecules, and a few other trace metal molecules. On the chemical - molecular level, the etchants contain some powerful solvents that can blasically unglue electrons from the Fe atom. Etchants attack the electron-rich Iron molecules, swiping electrons and generally causing molecular havoc for the hapless Fe molecules on the surface. This process leaves behind a powdery residue of loosely piled carbon molecules (the greyish and blackish appearance after you etch is this). Since the molecules in the tempered area are crystalline from the rapid cooling of the tempering process, there is a different rate of etching, and a deep etch will reveal different chatacteristics in the steel.
You can use etching to discover things about the temper of the blade too, like if it was quenched too fast (and thus is too brittle) or if it was cooled too slowly (resulting in too soft a blade) This is a whole discipline unto itself, and borders on alchemy and metallurgy.
Etchants:
The chemicals mentioned above do act at different rates, and a few will work well on other metals as well. Some acids can give off nasty voaltile gases when used to etch cetain metals, so do familiarize yourself with the chemicals and safety proceudres ahead of time. Etching with natural strength agents like carbonated soda, fruits, veggies, vinegars, wines, etc is relatively safe, and a good place to start your etching.
Resists.
After you get some stuff to etch, you can use certian tapes, markers, paints, and waxes to coat the blade, then you draw out some designs and cut/draw/scrape thru the resitst, so that metal is exposed. that will be the part that gets etched.
The resist is called that because it resists the etchant, ensuring that the area it covers does not get etched.
You dump the piece in the etchant, then when you finish etchig, you fish the piece out, neutralize the remaining etchant, and removwe the mask.
Oops. I guess I always have something to say about etching. What does this have to do wuth khuks? Well, ...something...
Keith