To be as invisible as possible, pins in a bolster should be the same material as the bolsters. Titanium is tough and light, but it isn't like working carbide. I don't see why you should have any problems pinning Ti with Ti pins.
I get guys coming in the store with titanium wedding bands that are scratched and dinged. They are upset, because they thought titanium is supposed to be a really hard metal. I tell them that titanium bands are lighter and stronger than gold, but the metal is a cousin of aluminum, not diamond.