Up until about 1993, the formulations for amorphous metals required cooling at about a million degrees kelvin per second which meant there were relatively few manufacturing methods that would work (spinning a glob out on a cooled plate, sputtering the material through a water jet). At Cal Tech they found that by using metal alloys composed of molecules of very different sizes, that they could slow down the movement into crystals, so that the cooling rate was 10's of degrees kelvin per second instead of a million. This still limits the thickness of casting somewhat but opens the door to a much wider range of applications. The per mold cost is (anecdotally) around $25K, and the actual casting equipment is very expensive (hundreds of thousands to millions of $$$).
This is all from memory, but the LiquidMetal thread started by R.W. Clark has all of this in a lot more detail.