If your knife edge both chips or rolls under light use, something is wrong with either the steel or your sharpening technique. Chipping indicates low toughness. Rolling indicates low strength. Also, sharpness has nothing to do with edge angle. 40-degree edges can be sharper than 25-degree inclusive edges.
When S30V came out, there were many reports of chipping. Those complaints have mainly disappeared as manufacturers have learned how to treat and sharpen the steel, but you could have a bad blade, although I think it's more likely in your sharpening technique. You might try sharpening it without diamonds to make sure you're not leaving deep scratches that facilitate chipping. Ankerson just went through a test of a S110V blade than another person was having trouble with chipping, but Ankerson sharpened it up and it worked fine. We don't know what the difference was in those two experiences, but sharpening technique would be an obvious candidate.
S30V is a really good steel that offers a nice blend of strength, toughness and wear resistance. S110V will give you more wear resistance, but less toughness (and so be more prone to chipping.) Rolling would most likely be reduced by increasing hardness -- going with a higher Rc, such as 60 Rc or higher. (But going higher in Rc can reduce toughness and resistance to chipping.) Powder steels can generally be taken to a higher hardness, have better wear resistance and offer finer, better distributed carbides that are less likely to be ripped out and appear as micro chips.
I'd guess that M390 or its variants would do everything that you need. M4 is excellent, also, but it's not stainless. Elmax is probably the toughest of the stainless steels, so it would most resist chipping.
I'd echo Ankerson that going with a better blade geometry might be a better choice for you than trying to make an acute edge do all the heavy lifting by itself. My Sebenza is 0.017 inches behind the edge. The mini-Rukus that I just bought is 0.020 behind the edge. I find that to be a nice range, but few manufacturers advertise edge width on their blades.