Originally posted by Ed Fowler
I have one problem, I have fallen hopelessly in love with 52100.
Now wait just a minute, Ed. I thought Kevin McClung said he'd never seen anybody cut anything with a bearing?
Grapevine,
Lots of good answers so far to the question you've posed. If there's one common thread in the responses thus far, I'd have to say it revolves around the issue of grain size and structure. In simplest terms, your low alloy, high carbon steels tend to have a smaller and more uniform grain structure than that found in your typical production stainless blade. The forging techniques used by some bladesmiths (most often with the high carbon steels) can further refine this grain structure. Many of the advantages you see associated with carbon steels (i.e. takes a fine edge, is easy to sharpen, withstands hard impacts, etc.) can be attributed, at least in part, to this grain structure.
Stainless steels, on the other hand, by definition, contain high percentages of chromium in their chemistry. Some of this chromium reacts with the carbon present to form chromium carbides, and, as I think most would agree, there are pluses and minuses associated with the presence of these carbides in a blade steel. For one thing, they are harder than the surrounding steel. Thus, in theory, they can contribute to better wear resistance, while, at the same time, also making the blade more difficult to sharpen.
But I think it's even more important to understand how these carbides can react during the actual steel manufacturing process. As the steel is poured and begins to cool, these carbides have a tendency to seek one another out and clump together, if you will. Obviously the uniformity of the stainless steel's grain structure can suffer as a result. A fair portion of the concerns you hear being raised with respect to stainless steel's propensity for being brittle or chipping out can be traced back to this phenomenon.
To be fair, the quality of the heat treatment plays a huge role in determing just how prevalent any of these potential shortcomings may become, but even at that, the relative simplicity of the heat treat regimen again appears to favor the low alloy carbon steels. This is more of a factor in production blades than it is in the custom knife community (where much greater care can be afforded to the heat treatment of each individual blade).
Finally, it's worth mentioning that companies such as Crucible have overcome many of these perceived grain structure related shortcomings in stainless and high alloy steel through their unique manufacturing processes.