3V:Why aren't more companies using it?

Sal Glesser said:
I would go so far as to say the particle metalurgy makes a bigger difference than often thought.

We don't normally get to CATRA test really similar chemistry with PM & non PM mfr. The opportunity to test CPM-154 was good for us.

CATRA testing of 154Cm and the powdered version showed the CPM version to have signifant improvement in abrasion resistance with relatively the same chemistry.

In the cas of a PM like ZDP-189, one could argue that the better performance was the result of "better" chemistry (3% carbon, 20% chrome). But in the case of the CPM-154 vs 154Cm, the difference in the process is is more obvious.

sal
I've been reading up on some stuff and found that the steels 3V, 1V, 10V, etc., don't form any chromium carbides, all of the chromium goes in to the matrix. With the full 7.50% chromium in 3V (or around there anyway), should put the corrosion resistance of 3V right along with D2. Conventionally cast 3V has chromium that forms carbides (though this steel isn't actually made that I'm aware of). I was just stating all this to further the discussion on benefits of CPM.
 
Jerry Hossom said:
In both cases the total carbide content of the steels was deemed insuffient to provide the needed strength, resulting in the plastic deformation noted.

I realize Crucible is really strong on promoting high carbide volumes however the work done by Roman Landes and Verhoeven argues for a lack of primary carbides in the edges because they are far too coarse to provide any support for the steel and tear out in use and weaken the edge. Landes has micrographs showing this for various steels, it was the focus of his PhD thesis which was published, however unfortunately has not been translated yet.

Consider if this general hypothesis were true then steels like INFI would also readily deform at the edge as they have far less primary carbide than S30V. How about steels like S7, or AEB-L which has no primary carbides at all. Do you have any published materials data on 1V vs say 52100 which shows it is weaker at the same hardness? I would be interested to see specifically the torsional, compressional and tensile strengths especially in low cross sections.

Kohai999 said:
The evaluation of a blade, and not the wielder, can be tested, in rope cutting, by building a specialized machine.

What you have to be aware of when measuring is what is actually being measured. It is the actual variances in a person vs a machine which are critical to the evaluation. Consider for example if I built a machine which tested sneakers by applying a specific compressional load to the sole in a uniform manner and then a lateral push. Would anyone really argue this is meaningful to how a sneaker would wear if a person wore it - then it isn't scientific. Scientific just means you gain information, people were doing scientific research long before there were machines.

I think that anyone willing to cough up around $100,000 US dollars, give or take, would be able to procure said machine.

Do you really think it is impossible for a user or knife maker to develop and refine his knives without such a machine? To be frank, if the difference in performance is so small that it takes extreme measures to see it then it is obviously of no consequence to the user or maker because they will never notice it in use.

Another problem not mentioned, is that manilla hemp rope is highly variable with regards to abrasiveness and consistency from batch to batch. Until a rope can be obtained that is made specifically for cutting, I am afraid that these variables could possibly skew test results.

Use more than one sample, there is always going to be sample variance. Ideally you just want it at a level so that it doesn't dominate the measurements. You have to do a number of trials anyway. Ideally you would repeat it on different blades from different steel batches and different heat treat batches to see the total spread of performance.

Sal Glesser said:
... it's a "competition", not just a test.

No arguement, though you can bet that it is going to turn into a huge promotion pushing knives and especially steel if the right person wins. It would be more impressive to me to see makers enter with inexpensive carbon and low alloy tool steels. Do you really need 3V to cut a 2x4 when Kevin Cashen has said you can do that with mild steel and still shave? I see it as similar to the STIHL series competitions. These are *not* used to promote the axes as actually working tools, they are actually cast stainless and they break readily on anything other than clear wood, they are used to showcase the extreme skill of the individuals. What I would personally like to see is a competition which was more like this :

First event - sod cutting:

-You have to remove a 4x4 patch of sod in one foot wide strips which is going to be used to form the roof of a shelter. You also have provided a one foot section of 2x4 so you can either use the 2x4 to make a tool or just cut it with the knife. The winner gets a score of 100 and the rest are scaled with time. You get zero if the sod strips are not self supporting.

Second event - fire making :

-You are given a four foot length of 4x4 and a ferro rod and have to bring one litre of water to a boil. The scores are again scaled in time.

Third event - steel cut :

-You are given a 4x4 piece of mild steel nailed to a frame, you have to cut a 2x2 hole in the middle. You have a 26 oz framing hammer and a one foot length of 2x4 available for batons. Score is scaled with time.

Forth event - turkey cut :

-You are given a large turkey. You have to reduce it to form for stock. All the fat is trimmed, and wing tips removed, leg/wing joints separated, breasts and tenders removed. The score is again ranked in time. The cuts are also judged for acceptance and you fail if they are below tolerance (joints not cut in the right place so the marrow is visible, the tendors or breasts are torn, etc.).

Fifth event - "arrow" removal :

-A 6" spike is nailed half way into a piece of 6x6, remove it by any means necessary. The score is scaled again with time.

Sixth event - rope cutting

-Cuts are made through one inch hemp rope on both a push and a pull (two inch draw) on a scale. Five cuts are made evenly from the choil to tip, the maximum force is recorded each time. The scores are ranked by the force applied. You get zero if you fail to make a cut on any attempt.

And finally - sharpening :

-A standard benchstone is provided throughout the event. The time spent sharpening is recorded and the scaled time is used as the score. This is 50% of the total score and the other 50% comes from the score of the other events. The order of the events are random and will change from one competiton to the other. The specific events are not critical, the general idea is just to give a very wide range of tasks and make it impossible for a knife to actually be optomized for all of them and include work commonly done by tactical/survival knives as well as bushcraft/hunting knives.

As well give the user the ability to vary technique to suit the knife. The knife for example in the sod cutting can go through the sods way faster than using the wood, however on a brittle steel the edge can chip or fracture badly and thus really cost time in sharpening, especially if the grindability is low. Similar for the hammer vs wood baton. A really tough knife will take the heavy hammer hits and chew through the metal but a brittle knife has to rely on the wooden baton and go much slower. Same for the fire starting and nail removal, a very strong knife can be used much more aggressively and will take apart the wood much faster.

-Cliff
 
Thomas W said:
FYI, we are using 3V in our Zero Tolerance, Ken Onion designed fixed blade, model 0100. Should be shipping this month. 3V is production challenging to be sure.

note the word "challenging"

it really means its a BIG PITA! :D
 
Larrin said:
I've been reading up on some stuff and found that the steels 3V, 1V, 10V, etc., don't form any chromium carbides, all of the chromium goes in to the matrix.

I would like to read that data, the low corrosion resistance of 3V was one of the common critisms of that steel. Note when people refer to X carbide in steel it doesn't mean it is pure X carbide, just X rich or mostly X. However the primary chromium rich carbides dissolve readily above 1900 F and thus at the high austenization temperatures those steels are usually hardened the primary chromium carbides will be mostly dissolved. However you would expect secondary chroimum carbide precipation during quenching as well as tempering.

-Cliff
 
Interesting tests you propose Cliff.

The tests are still being developed. It's very difficult to create challenges that test the design, material and cutter and still be interesting to the observers.

Much time has been spent thus far in developing this competition.

Any and all suggestions are appreciated.

Perhaps Ed can ad info.

There are also many other factors in the competition, like safety, training, inspection, etc.

sal
 
Cliff Stamp said:
I would like to read that data, the low corrosion resistance of 3V was one of the common critisms of that steel. Note when people refer to X carbide in steel it doesn't mean it is pure X carbide, just X rich or mostly X. However the primary chromium rich carbides dissolve readily above 1900 F and thus at the high austenization temperatures those steels are usually hardened the primary chromium carbides will be mostly dissolved. However you would expect secondary chroimum carbide precipation during quenching as well as tempering.

-Cliff
It's contained in the patents for 3V and 15-20V. Go to freepatentsonline.com and then search for patents assigned to Crucible. There is lots of information contained in them, there is also one for S90V which is quite interesting. You won't get very far searching for S90v, but searching for 420V and 3V might get you the patents too.

Edit: I'm aware of the carbide rich issue, etc., but with just 5% vanadium carbide volume (and that's it according to the patent), and vanadium carbide being one that will have most if not all vanadium in it, I think that most if not all of the chromium and molybdenum is in solution after heat treating 3V. This is some speculation of course, but just looking at those numbers I don't think it would be a stretch to say 3V and D2 have comparable corrosion resistance. As a side note, Dick Barber says 5-7% chromium is in solution in D2.
 
I've never noticed any meaningful tendancy of 3V to corrode. I'd say it's about the same as D2, maybe better because it will generally take a finer finish which is less likely to trap moisture.

I had noted some time back that when I encountered corrosion on 3V it tended to appear in spots (not a general bloom as on tool steels), and in many cases those spots sit atop a pit in the steel which is not nice. I now passivate my 3V blades and have not had that problem in quite awhile. I was told those spots were likely the result of oxide contamination in the steel and that Crucible was working on eliminating that problem. That was a few years ago so maybe they cleaned it up since then.

In my opinion 3V is the "best all around knife steel"*** made, assuming you're willing to dry it off once every few days.

I'd caution against trying to apply a general understanding of steel chemistry and how steels are formed to the steels made by the CPM process. It's a different beast.

*** means different things to different people.
 
Sal Glesser said:
Interesting tests you propose ...

Kevin McClung origionated the metal cutting as a test of tactical knives, he used it to promote his knives to free someone from a car before emergency responce would arrive. The 4x4 fire starting is done frequently in lumberjack competitions only they start off with a much larger round of wood and an axe of their choice. But as I noted the exact tests really don't matter as much as what they cover and that you want to test the complement.

If you have something which is well suited to a very thin tip you should also have something which is well suited by a very strong one. This gives everyone the ability to showcase their knives. Someone with very tough knives for example could set all the records in the heavy events, someone could focus on the opposite and set all the precision cutting and others could showcase a balanced design and have the best total score.

This would then allow a user to look at the tests, see which kinds of uses he wanted and then see what kinds of steel and blades did well at those tasks.

Larrin, thanks for the reference, very interesting reading. Here is a list of patents by Crucible for those interested :

http://www.freepatentsonline.com/se...spat=on&date_range=all&stemming=on&sort=chron

This one is in particular of specific interest to the above :

http://www.freepatentsonline.com/5989490.pdf

Specifically :

"It has also been discovered that in comparison to conventional ingot-cast tool steels with compositions similar to those of the articles of the invention, that production of the articles by hot isostatic compaction of nitrogen atomized, prealloyed powder particles produces a significant change in the composition as well as in the size and distribution of the primary carbides. The former effect is a hereto unknown benefit of powder metallurgical processing for cold work tool steels, and is highly important in the articles of the invention because it maximizes the formation of primary MC-type vanadium-rich carbides and largely eliminates the formation of softer M.sub.7 C.sub.3 carbides, which in addition to MC-type carbides are present in greater amounts in ingot-cast tool steels of similar composition."

The amount of primary chromium rich carbide in 3V was found to be < 0.5%. Given the volume fraction of primary carbide is so low, as long as secondary carbide precipitation is minimized there should be minimal bound chromium. This raises an interesting question as to why people had frequent problems with 3V and rust compared to other tools steels in general.

Note with D2 the amount of chroimum free is strongly dependent on the austenizing temperature as it is with stainless steels in general. This is why you see comments about some D2 being very stain resistant because some people are soaking it very hot to dissolve the chromium and quenching it in oil to prevent precipitation.

One of the more interesting points noted was that the dependance of toughness on primary carbide fraction was found to be independent of the type of carbides and thus you can maximize toughness at a given required wear resistance by having the hardest carbides at the lowest volume.

-Cliff
 
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