As to where the silicates are in the leather, I'm no expert. However, I do know that I really like the results I've been getting with my strops since I started sanding 'em.
My next question would be, 'Why are the silicates only in the outer layer/surface of the leather?' What process (natural or process/tanning-related) would result in the silicates being present only on the outer surface?
Good questions!! First off, we need to remember that there are 'natural silicates' that are present in the skin that come from the foods the animals have been eating. Eat more grass and get more natural silicates. This is why horsehide usually has more silicates than cowhide. Cows these days are generally force-fed to fatten them up for market, getting very little natural grasses in their diet.
Then there are chemical silicates that are used in the tanning process. Chemicals such as sodium aluminum silicate are used in the 'Chrome tanning process, but don't remain within the hide after it's finished. These silicates get washed out of the leather in the final production process.
As for why there can be more in the outer layer of skin... this comes from a process known as 'boning.' Leather starts out with natural silicates all through it. Rubbing the leather with a rounded end of a stick (like a 'souvenir' baseball bat or, as was used, the end of the thigh bone of a cow,) while it's damp and pliable will force more of the natural silicates to the surface. This process used to take days of hard hand labor and produced the fine 'Russian Leather' (the name of the process, not the location) barber strops. Today you can expect to pay in excess of $100 US for a high quality horsehide strop which has been machine 'boned.' You can really feel the difference when you put a blade to leather like this. It almost grabs the metal as you strop.
I can understand how some strops are specially treated/moisturized at time of manufacture, to make their surface more supple and/or 'grippy'. In those cases, I can see how sanding might make them less effective. But, in the case of simple tanned leather, I'm not so sure it would degrade performance much, if at all.
The majority of razor strops today are not boned. The leather IS treated, but treated for longevity, not to make it more grippy. Mink oil, Lexol, etc., any good leather conditioner will work. The leather found in the bench strops sold by woodworking and knife shops most likely hasn't had ANY treatment at all! It just plain vegetable tanned leather glued to a block of wood. You can make one just as good for 1/4 the price. If you're going to use any kind of compound on the leather, buy the cheapest piece you can get that is still flat and smooth. With compound, it doesn't even need to be vegetable tanned. In fact, with compound it doesn't even need to be leather.
The ONLY reason to use leather as a strop is for the natural silicates which are smaller and finer than compounds. If you want a leather strop that REALLY does what a strop is supposed to do, get a nice piece of cordovan horsehide cut from the 'shell' of the hide. Once you use a strop like that, you will never use anything else again. You really have to 'drag' the knife across horsehide. It doesn't slide...
But you have to remember... a 'good' strop is the final step. Compound is a step before a 'good' strop.
Stitchawl