Heat Treatment - Crystal Weaving Foundation

20180324 HT 2.5:

HRC at peak/highest and at 400F tempered:

A2 67, 64 https://www.alphaknifesupply.com/Pictures/Info/Steel/A2-TC.gif
Cruwear 67, 65 https://www.crucible.com/eselector/prodbyapp/tooldie/cruweart.html
RWL34 66, 65 http://www.damasteel.se/files/8414/5670/2913/flyer_rwl34_A4.pdf
Becut 63, 60.5 http://www.bestar-steel.com/wp-content/uploads/BECUT.pdf
440C 65, 63 https://www.alphaknifesupply.com/Pictures/Info/Steel/440C-TC.gif
W2 Chopper 67, 65
CruforgeV Chopper 66, 64
https://www.alphaknifesupply.com/Pictures/Info/Steel/CruForgeV-TC.gif

20180325 HT 2.5, HRC peak, 400F, 500F tempered:

S110V 66, 65
M2 67, 65
M4 69, 67, 65

* also at 500F 10V/65, 4V/64.5 and some M4 at 64-64.5rc, s690/65

20180326:
Tested Cfv & W2 choppers - edge failure mode = rolled, with repeated impacts (aluminum tubing) rolled eventually micro chips. W2 is probably 64rc rather 65rc from impact but could also because edge is a tad thinner than cfv.

Tested A2 64rc - passed whittled african blackwood, beef rib bone *with nano rolled, feel but can't see, verified with 22x loupe. chop beef rib bone(brb) = rolled -> ripple -> micro chips. A2 64rc performed very well. Will look into making chopper, especially it is much easier to grind than cfv.

Tested M4 67rc - pass whittled AB but micro-chips at brb. Chop brb = micro chips almost twice as large as A2. Will re-test M4 at 65rc.

Est W2 grain diameter is less than 1.5um (geez! accidental snapped tang while doing a dumb cold straightening). Grain refinement is faster & more effective now.

64-65rc edges seem excellent for high end user/usage which would supports impact & hard edc uses with edge geometry ~ edc: 15dps, 0.01"BET impact: 18dps, 0.02"BET.

20180327:
Heavily chopped & batoned hard woods with Cfv chopper - easy passed.

W2 chopper is 1/4" thick 10.5" blade but only 1.5" wide, so I distal taper to around 0.11" spine near tip. It's more like a knife toward the front with overall 15dps, 0.012-0.015" BET. Chop fairly deep into wood even though it lacked chopper momentum. Quite impressed how this thin edge withstand heavy chopping.

20180329:

After some triangulating my ht for many steels - there is some correlation between silicon excess of 0.4% lead to edge instability at high hrc. Si is an austenite stabilizer, so stabilized RA% is proportionally to poor keen edge holding, also mushiness (weakened) edge failure. Si% in many Crucible PM steels are unnecessary too high in 0.8-0.9% range, with cru-wear at 1.2%Si. Except for 10V & 15V extra high C% which would benefit from additional Si%.

Elmax 0.8%Si and M390/20cv 0.7%Si are the other 2 steels, which I mostly will avoid when ht for 64+rc working hardness.

20180330:
After some retrospective looks at sub micron edge holding/retention (fresh sharpen & sealed - hence remove corrosion factor) for various steels. I think, element volume% sum(Cobalt + Silicon) is proportionally tied matrix slip/yield at nano level. Which dictate matrix yield strength at sub micron level - translate to apex width degradation rate.

For 2-3 years now, I couldn't pinpoint why 52100 has better nano edge than W2 (both steels from NewJersey SteelBaron). Respectively, it is 0.07%Si vs 0.21%Si. Blue#2 has 0.16%Si, which seems to has good apex retention width between 0.7-1.0um very well. 52100 sub 0.5um, W2 1.0-2.0um. aebl 2.0-3.0um. niolox 0.5-1.5um. so on... depends on Co+Si element volume%.

Co localize affected matrix is around 45hrc. Si localize induced RA around mart unit & particle matrix is basically at ferrite level - 20 to 26hrc. For high Co% steels, such as maxamet 10%Co + 0.25%Si, sub 2um apex has higher yield strength than with 0.4%Si.

63-64rc overall matrix probably allow 0.2um thinner apex than sub 61rc.
65+rc overall matrix probably allow 0.3um thinner apex than sub 61rc.

^ both can't negate Co+Si affect. So 64-65rc is a good balance point of edge retention (given edge support intended load/usage).

So for good sub-micron edge shaping & holding, I will re-test njsb 52100, cruforgeV, blue#2, niolox. All assuming their CA Specs on Si% is correct. Niolox has good corrosion resistant due to 12.7%Cr however later on I need to further analyze whether Cr acts as a lattice slipper or blocker. At this point, Cr looks like a blocker, since fracture is common failure mode Cr rich matrix.

Other elements on the same periodic table line as Si are most likely be as bad but I ignored them because most steels are relatively clean. Of course, when sum mass% getting past 0.05% - time to pay attention and perhaps avoid such steels.
 
Last edited:
I thought s125v & 15v were posted/mentioned already. OK, I did but only in a PM.
Most of my blades, today, have field grade (scratchy 120 grit finish). So these steels weren't that more difficult to grind and sometime feel easier than niolox (weird eh ;))

rXJ4JQn.jpg


While those ^ knives are receiving oil coats... Below are WIP
iLMnhKu.jpg


I will put more-brain into ht - aim to yield a working 63+rc vanax. Awesome corrosion best to pair with awesome strength :p ... 45% chance of success - yup, quite optimistic!

Luong,

You are holding out on us:eek:
I have seen pictures of HT 2.5 with s125v at 66rc, 15v at 68rc, and vanax at 62rc??!!!

Vanax is looking increasingly positive - but s125v? Didn't know you were such a glutton for punishment:D

Update 20180410:
Ht 1 vanax and 2 niolox blades together in a heat. I over modified vanax so end up with excess RA%, hence only got 61rc working hardness = failed = fixable if try again however not worth burn more $ on vanax. Niolox (raw) peak hrc 65 (~ 65.5-65.75 cleaned), expect around 64rc @ 400F tempered.
A 10v 5.5" full tang petty blade killed a bunch of belts and I blinked - put 3 divots on the bevel = blem boog! Well, this 1.3 oz (blade only, maybe 3 oz finished) probably will end up in my kitchen knife block.
WIP above includes - 1 niolox util/BT and a s30v hunter/fighter. 2 niolox blades hted today will be in next WIP/batch.
Tested 440c 63rc/400F tempered - edge has flat spot (0.5" long) when hit some metal in cardboard. Overall seem promising at 63rc. Next time, I should test at 64rc/375F.
 
Last edited:
Thanks Chris!

For the next 2.5 weeks, I'm accumulating finished & to-be-hand-sand+oil handle knives before BCMW gears are packed in moving boxes.

Luong,

When is the next BCMW stainless sale? :thumbsup:

Oh heck - let burn some $, I want to accumulate at least one 63rc vanax blades before shutting down my ht gears. Probability of success - went way down from early false optimism - is 15%.

Edit 20180411 PM:
Tested vanax 14dps, 0.010" BET - passed whittle ebony & African Blackwood. Umm shouldn't be - only 63+rc edge pass AB whittling. Test 2 prev 61rc vanax blades against AB - both have big rolled. This vanax easily abrade prev 61rc vanax. Anyway, after a few scraping tests against 63-65rc blades, this vanax edge area is harder than 63rc. Yay! and LOL spine area is clearly around 61rc. Yup, this vanax blade hardened differentially by accident. I certainly will use this feature later.

Tested whittle dried cooked beef rib bone - micro rolls. Will take a closeup pic later.

So my vanax chem mod worked. Once new bar arrives, I will repeat ht except avoid differential (consequence of time saving step).

FFFRNQi.png
 
Last edited:
packing? moving boxes? shutting down ht gear?
Should we be getting worried?
As always, I am happy to provide money for you to burn:D
 
I've a couple more weeks messing around before packing up my gears. Vanax bar should arrives in time for weekend HT tinkering... will see how fast my dragster-1st-speed I can setup a new shop.
Thanks for the 1T USD offer but burn cash to keep warm seem wasteful, not to mention environmental unfriendly :p

packing? moving boxes? shutting down ht gear?
Should we be getting worried?
As always, I am happy to provide money for you to burn:D

Extensive tests 440C (ESR ingot) 63rc/400F-tempered varying from 12 to 15 dps, 0.010" BET, 1K to 5K waterstone refined edges = *extreme edge stability*
Passed all normal std tests. Edge has barely visible deformations (ripple, roll, flatten) from whittled a nail. Affected areas just skid against nail, i.e. loss its bite/dig. Edge keenness quality seem to reflect very clean steel. Under 22x loupe, no odd large size deformations, surprising uniform in size.

Today I will grind the 2 of 5 s110v 65rc blades and prepare a few D2 blanks for ht. S125V 66rc & 15V 68rc will get their first edge for testing as well.
 
Maybe I saved a luck for last. Received Vanadis 4E yesterday, today did a near perfect ht & tested a field knife a few hrs ago.

V4E 64rc edge rolled after chopped brick & cinder blocks. I didn't have a chance to test that partial tang m4 64.5rc yet - as intended for side-to-side comparison against v4e.

Peak HRC: v4e 67, m4 68

This is my last ht batch for a while.

cTCWJU4.jpg
 
Last edited:
Maybe I saved a luck for last. Received Vanadis 4E yesterday, today did a near perfect ht & tested a field knife a few hrs ago.

V4E 64rc edge rolled after chopped brick & cinder blocks. I didn't have a chance to test that partial tang m4 64.5rc yet - as intended for side-to-side comparison against v4e.

Peak HRC: v4e 67, m4 68

This is my last ht batch for a while.

cTCWJU4.jpg

I want the top knife :D
 
Test edge stability by pressure cuts raw pork rib bone with thin edge geometry for s125v 66rc and 15v 68rc

HT 2.5 - pro user specs, 2150F aust, 400F tempered

Edge geometry: 15dps with 18dps micro bevel (at DMT E - 12um mesh).

CPM S125V 0.09" thick, 13/16" wide, 3.75" edge
0.060" behind edge thick

CPM 15V 0.085" thick, 7/8" wide, 3.8" edge
0.007" behind edge thick

9:23
 
:cool: I will put handles on these V4E blades and stress-tests (maybe destruction) a 0.150" thick one.

Get in line, buddy :p

I will try to shoot a video of a thin 0.150" lops young & ripe coconuts and chop some bones.
Duh, didn’t know it’s yours :eek:
Next one then ... :)

My LN2 dewar has about 5L, so rather than let it evap. Today, I will ht a M4 chopper & a few older 10V hunter profile partial tang blades. Accumulating blades mode...

edit 20180424: *M4 575F tempered 64.5rc has much better edge stability than 500F tempered, esp tapping at dried cooked beef rib bone. At 500F tempered there were small chippings and signs of low ripples/plasticity when taps(short swing chops) these hard bones
 
Last edited:
Found: video of ht protocol


interesting video description
The goal is to build a strong & tough solid using identical shape small building unit. Between units & group of units - interconnection, gap and vacancies determine strength & toughness of the result solid.

I use Combinatorial Optimization Graph to distilled 2 optimization goals:
* Maximize interconnectivity between units
* Minimize solid volume & radius

Conceptual to build highly interconnected crystal via 2 steps process:
* Create a outter structure frame by weave a hatch or spiral frame and formed tight pack inner/pocket/trap volume
* Convert inner/trapped volume to final crystal form & lattice

CWF HT - Applied to Steel Heat Treatment - FCC/Aust & BCT/Mart crystal lattice.
* shallow hardening - fast cool to avoid Pearlite Nose, then begin step1
* obj = work piece/blade
* please read http://www.reluctantgourmet.com/smoke-point/ Points: smoke ~400-480F, flash ~600F; fire ~700F.
* fill hot oil bath 2/3 full - leave room for oil thermal expansion in volume

s1: quench obj to 450-465F oil bath, slice around for 10 seconds, then stir around for 1 minutes
* do this for 1 or more objs
* Suspend/hanging this obj in this bath

Explanation: build the outter structure by minimize fcc phase change to bct driving/pushing force and at the same time induce pulling force, hence change of lattice orientation

s2: Cover the oil bath with a lid or aluminum foil.
* Target for uniform 1F/minute drop in temperature.

s3: 1 hr later - remove lid/cover.

s4: When oil temperature falls below 200-180F (take around 2-3 hrs depend on oil volume), air cool the blade to near room temp (~70-90F)
* ok, to leave obj overnight or a year

s5: Wash/clean blade. Straightening if needed and easy because the blade is still highly ductile(very high RA%) at this point
* ok, to leave obj overnight or a year

s6: Cryo (subzero should be ok for many steels) for 3-4 minutes, take out, wash
* ok, to leave obj overnight or a year

Explanation: Via thermal contraction (reduce atomic radius) to nucleate/calving strain/dislocated points, setting up for HCP precip. BCT outter structure will contract less than trapped/inner FCC pockets.

s7: Soak obj in 275F oil for 5 minutes. Take out & wash.

Explanation: hcp precip + Via thermal expansion (increase atomic radius) - spatial now allows retained-austenite conversion to martensite

CWF HT is done. Obj rc should be at peak hrc for maximum wear and very good toughness.

Temper ONLY when warranted by intended usage requires more ductility.

Use whichever appropriate Aust temp per specific steel as if doing conventional ht. Except with good CWF HT temperature control (1F/minute cooling), high alloy steels should aust about 50F higher than maximum mfg recommended aust temp.

e.g. aust temp (recommended but not necessary temp I use)

Low Cr high carbon steels (108x, 109x, 52100, w2, etc..): 1450 - 1475F
* need to avoid pearlite nose with interrupt quench with fast quenchant to drop blade temp before 1000F before quench in hot oil.

Aeb-l & similar: 1950-1975F

Mid & High Cr steels: 50F above mfg maximum recommended aust temp

Mid& High Cr with Nitrogen added: mfg recommended aust temp range

Just want to avoid confusion about soak at 275F - energy at this temp + dislocation is mostly (99+%) below activation for phase change of martensite to something else. So I avoided use 'Tempering'. IME 315-330F temp range definite showed clear sign of tempering (mostly mart to cementite precip). Near 250F where I found thermal expansion (increase atomic radius) clearly taken place, so workable soak temp range about 240F-300F. I used a convection toaster oven (with at least 20 minutes preheat to stabilize temp), so 275F +- 25F flux worked fine thus far.


and some comments on that video...

Continuous uniform cooling is the key. Marquench is mostly to sneak below bainitic transformation zone. For air harden steels + Infrared Thermometer, you can cool until below 475F then cool slowly in liquid (air won't work of temperature fluctuations). Here is a good lecture on kinetic of transformation

While at it watch the entire lecture series (some repeat info) - that will give you a good idea (and maybe just exposure) on metallurgy.
^i subscribe to that yt channel and it has some very interesting videos on steel specifically that series he links to.

does the martensite transform to lath or plate?

More extreme fine version of lath - weaved :) Plate mart is a bad thing.

Weaving concept is about slow & control crystal formation/phase-change. So yes, 1F/minute cooling from 275F to 200F is ideal but in practice, it's hard to discern benefits. Naturally, when performance differences is less than 10%, data of in-hand tests drown out by biases/noise/errors. Also in concept cryo quench cooling rate should be slow & stead - perhaps, hang blades above LN2 to cool (hahaha if you have a large dewar with long neck).

I let blades soak in 275F oil tank and let the tank & blades air cool until 200F. Otherwise due to impatience and or laziness, I take blades out and dunk in water.
 
Last edited:
I still have that knife i won in the giveaway. Its absurd how long its held a razor edge, and its been on kitchen duty for a while now. Its held up amazingly. I won't pretend to understand the science behind the process but the end product seems to be great.
 
I am still w/o a shop ... Test below has something to do with Newton's Laws of Motion Inertia Frame of Reference for moving object.

Testing a field knife ability at impact and shock.

Specs:
Vanadis 4E, 0.150" thick, 6.7" blade length, 8.5 oz
64rc via CWF HT 2.5

Sharpened:
18dps (degrees per side). freehand 120 SiC; EdgePro 180 SiC to burrs; EP 400 SiC to burrs and deburred; fh 600 diamond; fh 1200 diamond refined & cleaned apex.

Thickness:
0.015" at edge shoulder; 0.024" 1/8" up from apex; 0.045" 1/4" up from apex.

Primary bevel/grind slightly less than 4.7 dps.

Test materials:
2x4, oak, eucalytus, cardboard, pork rib bone, copper wire, thin tin can, 12D nail.


Edge after baton+chop+shock with/against 12D nail
mz2o3sx.jpg
 
Back
Top